authors |
Duarte, TAG; Santos, ICMS; Simoes, MMQ; Neves, MGPMS; Cavaleiro, AMV; Cavaleiro, JAS |
nationality |
International |
journal |
CATALYSIS LETTERS |
author keywords |
Polyoxomolybdate; Homogeneous catalysis; Oxidation; Hydrogen peroxide; Olefins |
keywords |
KEGGIN-TYPE POLYOXOMOLYBDATES; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; BIFUNCTIONAL CATALYSTS; POLYOXOTUNGSTATES; MONOTERPENES; EPOXIDATION; CHEMISTRY; ALCOHOLS; ALKENES |
abstract |
[PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation. |
publisher |
SPRINGER |
issn |
1011-372X |
year published |
2014 |
volume |
144 |
issue |
1 |
beginning page |
104 |
ending page |
111 |
digital object identifier (doi) |
10.1007/s10562-013-1101-8 |
web of science category |
Chemistry, Physical |
subject category |
Chemistry |
unique article identifier |
WOS:000330951700014
|