Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
authors Gozalvez, C; Zafra, JL; Saeki, A; Melle-Franco, M; Casado, J; Mateo-Alonso, A
nationality International
abstract Acenes have received a lot of attention because of their inherent and tunable absorbing, emissive, and charge transport properties for electronic, photovoltaic, and singlet fission applications, among others. Such properties are directly governed by molecular packing, and therefore, controlling their arrangement in the solid state is of utmost importance in order to increase their performance. Herein, we describe a new solid-state ordering strategy that allows obtaining 1D mixed pi-stacks of acene and azaacene derivatives. In addition, we illustrate that charge transport can be modulated by the electronic nature of the encapsulated phenazine, opening new perspectives in the design, preparation and development of supramolecular organic semiconductors.
issn 2041-6520
isbn 2041-6539
year published 2019
volume 10
issue 9
beginning page 2743
ending page 2749
digital object identifier (doi) 10.1039/c8sc04845b
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000459929800018
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journal analysis (jcr 2019):
journal impact factor 9.346
5 year journal impact factor 8.945
category normalized journal impact factor percentile 88.418
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