authors |
Liu, X; Zhou, J; Huang, L; Xiao, HP; Amarante, TR; Paz, FAA; Xiang, B; Fu, LS |
nationality |
International |
journal |
INORGANIC CHEMISTRY |
keywords |
TRANSITION-METAL-COMPLEXES; SOLVOTHERMAL SYNTHESIS; 2ND-HARMONIC GENERATION; ANTIMONY-SULFIDE; CHAINS; CLUSTERS; SELENOARSENATES; SEMICONDUCTORS; CONDENSATION; UNIQUE |
abstract |
One novel three-dimensional (3-D) copper(I)-thioarsenate(III) [Ni(en)(3)]Cu4As4S9 (1, en = ethylenediamine) has been solvothermally prepared with the utilization of the in situ formation of [Ni(en)(3)](2+) complex as structure-directing agent (SDA). 1 contains cubane-like [Cu8S12](16-) clusters and rare tetrameric [As4S9](6-) units, which are interconnected to generate the first example of a 3-D anionic framework [Cu4As4S9](n)(2n-), topologically identical to pyrite, and having large channels filled by [Ni(en)(3)](2+) complex cations. 1 is a potential wide-band-gap semiconductor with an energy gap of 1.91 eV that exhibits selectively photocatalytic degradation of methylene blue under visible-light irradiation. The density functional theory calculation, photocurrent response, and magnetic properties of 1 were also investigated. |
publisher |
AMER CHEMICAL SOC |
issn |
0020-1669 |
isbn |
1520-510X |
year published |
2021 |
volume |
60 |
issue |
9 |
beginning page |
6813 |
ending page |
6819 |
digital object identifier (doi) |
10.1021/acs.inorgchem.1c00703 |
web of science category |
7 |
subject category |
Chemistry, Inorganic & Nuclear |
unique article identifier |
WOS:000648429200074
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ciceco authors
impact metrics
journal analysis (jcr 2019):
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journal impact factor |
4.825 |
5 year journal impact factor |
4.501 |
category normalized journal impact factor percentile |
92.222 |
dimensions (citation analysis):
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altmetrics (social interaction):
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