resumo
The synthesis of three molecular nanoribbons with a twisted aromatic framework is described. The largest one shows a 53 linearly fused rings backbone (12.9 nm) and 322 conjugated atoms in its aromatic core (C296N24S2). This new family of nanoribbons shows extremely high molar absorptivities, reaching 986 100 M-1 cm(-1), and red-emitting properties.
palavras-chave
GRAPHENE NANORIBBONS; LADDER-TYPE; HYDROCARBONS; NANOGRAPHENE
categoria
Chemistry, Multidisciplinary
autores
Dubey, RK; Melle-Franco, M; Mateo-Alonso, A
nossos autores
Manuel Melle-Franco
Investigador PrincipalProjectos
Redesigning 2D Materials for the Formulation of Semiconducting Inks (2D INK)
Projeto de Investigação Exploratória: Manuel Melle (IF Manuel Melle)
agradecimentos
This work was carried out with support from the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country (Grupo de Investigacion GIU17/054), Gobierno de Espana (Ministerio de Ciencia e Innovacion, Plan Estatal de Investigacion Cientifica y Tecnica y de Innovacion), Gobierno Vasco (PIBA and BERC programmes) and acknowledge technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant Agreement No. 722951). This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreements No. 664878 and No. 899895. In addition, support through the project IF/00894/2015, the advanced computing project CPCA/A2/2524/2020 granting access to the Navigator cluster at LCA-UC and within the scope of the project CICECOAveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020 funded by national funds through the Portuguese Foundation for Science and Technology I.P./MCTES is gratefully acknowledged.