Catalytic activity of gold nanoparticles deposited on N-doped carbon-based supports in oxidation of glucose and arabinose mixtures
authors Franz, S; Shcherban, ND; Bezverkhyy, I; Sergiienko, SA; Simakova, IL; Salmi, T; Murzin, DY
nationality International
journal RESEARCH ON CHEMICAL INTERMEDIATES
author keywords Sugar oxidation; Gold catalysts; Glucose; Arabinose; Carbon support; Glucuronic acid
abstract Oxidation of a mixture of glucose and arabinose over Au particles deposited on porous carbons, N-doped carbons and carbon nitrides was investigated at 70 degrees C, under constant pH of 8, and oxygen partial pressure 0.125 atm. In particular, Au deposited on nitrogen-containing carbon-based mesoporous structures demonstrated activity in the oxidation of the sugars to the corresponding aldonic acids higher than gold deposited on undoped carbon supports (conversion of glucose up to ca. 60%, arabinose-ca. 30% after 200 min). The results can be explained by the basic nature of the supports leading to an increase in the polarity of the carbon surface and the oxygen activation. Glucuronic acid (with selectivity ca. 10-93.5%) together with gluconic acid was formed as a result of glucose oxidation, while arabinose was selectively oxidized to arabinonic acid.
publisher SPRINGER
issn 0922-6168
isbn 1568-5675
year published 2021
volume 47
issue 6
beginning page 2573
ending page 2587
digital object identifier (doi) 10.1007/s11164-021-04426-6
web of science category 15
subject category Chemistry, Multidisciplinary
unique article identifier WOS:000626798000001
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