Synthesis and crystal structure of copper and gold complexes of 1,2,5-thiadiazole-3,4-dithiolate. Charge transfer salt with TTF


The M(tdas)(2) complexes (tdas(2-) = 1,2,5-thiadiazole-3,4-dithiolate) with M = Cu-II, Cu-III and Au-III were obtained as tetrabuthylammonium and tetraphenilphosphonium salts and characterised. The crystal structure of (n-Bu4N)n[M(tdas)(2)], M = Cu(2) and Au(4) were determined by X-ray crystallography as well as that of the charge transfer salt (TTF)(2)[Au(tdas)(2)](2) (5). (C) 2003 Elsevier Science B.V. All rights reserved.



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Simao, D; Alves, H; Santos, IC; Gama, V; Almeida, M

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