abstract
Laser floating zone technique (LFZ) is used to grow directionally solidified eutectic (DSE) zirconia-mullite composite fibres (30:70 in wt.%). A notable increase in hardness is observed from 11.3 to 21.2 GPa as the pulling rate increases from 10 to 500 mm/h, due to the ultra-fine eutectics developed at very high growth rates. The indentation fracture toughness reaches a maximum value of 3.5 MPa m(1/2) for the fibre pulled at 100 mm/h, almost three times the value of 1.2 MPa m(1/2) determined for LFZ single-crystal mullite. The eutectic dendrites that develop along the growth direction are immersed in a glassy phase whose brittleness is counteracted by the beneficial ultra-fine morphology, giving a bending strength maximum of 534 MPa. Yet, the soft nature of the glassy matrix prevails at the high temperature testing (1400 degrees C), causing a decrease to about one-half of the RT value in the fibres with less glassy phase content. (C) 2014 Elsevier Ltd. All rights reserved.
keywords
CERAMIC COMPOSITES; MICROSTRUCTURE; FIBERS; SYSTEM; TEMPERATURE; WHISKER; SINGLE; ALLOY
subject category
Materials Science
authors
Carvalho, RG; Oliveira, FJ; Silva, RF; Costa, FM
our authors
Filipe José Alves de Oliveira
Principal Researcher
Rui Ramos Ferreira e Silva
Associate ProfessorProjects
acknowledgements
Work funded by FCT (Portugal) through projects CICECO PEst-C/CTM/LA0011/2013 and I3N PEst-C/CTM/LA0011/2011. Ricardo G. Carvalho also acknowledges FCT for a PhD grant (SFRH/BD/64891/2009).