Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES

abstract

Mixtures of non-ionic compounds have been reported as DES but most are just ideal mixtures. In the thymol-menthol system, an abnormal strong interaction was identified stemming from the acidity difference of the phenolic and aliphatic hydroxyl groups. This type of interaction is found to be the key to prepare non-ionic DES, that may be classified as type V.

keywords

PERMEATION; MODEL; DRUG

subject category

Chemistry

authors

Abranches, DO; Martins, MAR; Silva, LP; Schaeffer, N; Pinho, SP; Coutinho, JAP

our authors

acknowledgements

This work was developed in the scope of the project CICECO Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (Ref. FCT UID/CTM/50011/2019) and Associate Laboratory LSRE-LCM, POCI-01-0145-FEDER-006984 (Ref. FCT UID/EQU/50020/2019), and project MultiBiorefinery (POCI-01-0145-FEDER-016403), all financed by national funds through the FCT/MCTES (PIDDAC) and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement.

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