authors |
Paz, FAA; Shi, FN; Trindade, T; Klinowski, J; Rocha, J |
nationality |
International |
journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
keywords |
CAMBRIDGE STRUCTURAL DATABASE; CADMIUM-ORGANIC FRAMEWORKS; TRIMESIC ACID |
abstract |
The room-temperature crystal structure of the title compound, [Cu(H(2)pmida)(phen)]center dot 3H(2)O [where H(2)pmida(2-) is hydrogen N-(phosphonomethyl) iminodiacetate, C5H10NO7P2-, and phen is 1,10-phenanthroline, C12H8N2], was recently determined by Pei Lu, Ke, Li, Qin, Zhou, Wu & Du [Struct. Chem. (2004), 15, 207-210]. We report here a redetermination, at 180 (2) K, with greatly improved precision. Hydrogen bonds lead to the formation of one-dimensional tapes which run along the [100] direction of the unit cell. Adjacent tapes are interconnected via pi-pi offset stacking ( between the 1,10-phenanthroline ligands) and by hydrogen bonds involving the water molecules of crystallization. |
publisher |
BLACKWELL PUBLISHING |
issn |
1600-5368 |
year published |
2005 |
volume |
61 |
beginning page |
M2247 |
ending page |
M2250 |
digital object identifier (doi) |
10.1107/S1600536805031806 |
web of science category |
Crystallography |
subject category |
Crystallography |
unique article identifier |
WOS:000232965400040
|
ciceco authors
impact metrics
dimensions (citation analysis):
|
|
altmetrics (social interaction):
|
|
|