Highly emissive Zn-Ln metal-organic frameworks with an unusual 3D inorganic subnetwork

abstract

Mixed zinc-lanthanide (Zn-Ln) metal-organic frameworks (MOFs) based on the 3,5-pyrazoledicarboxylate ligand exhibit an unusual three-dimensional (3D) inorganic subnetwork and display highly efficient photoluminescence.

keywords

COORDINATION POLYMERS; ZN4O(ACETATE)6; SINGLE

subject category

Chemistry

authors

Liu, CB; Ferreira, RAS; Paz, FAA; Cadiau, A; Carlos, LD; Fu, LS; Rocha, J; Shi, FN

our authors

acknowledgements

We thank Fundacao para a Ciencia e a Tecnologia, FEDER, QREN, COMPETE, PEst-C/CTM/LA0011/2011, projects PTDC/QUI-QUI/098098/2008, PTDC/CTM/108975/2008, PTDC/CTM-NAN/119994/2010 and grant SFRH/BPD/44106/2008.

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