A layered erbium phosphonate in pseudo-D-5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation
authors Ren, M; Bao, SS; Ferreira, RAS; Zheng, LM; Carlos, LD
nationality International
journal CHEMICAL COMMUNICATIONS
keywords SINGLE-MOLECULE MAGNET; ION MAGNET; ANISOTROPY; COMPLEXES; DYSPROSIUM(III); BEHAVIOR; HYSTERESIS; DYNAMICS; EXCHANGE; BLOCKING
abstract A layered erbium(III) phosphonate compound, [Er(notpH(4))(H2O)]ClO4 center dot 3H(2)O (1), in which the Er-III ion has a pseudo-D-5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.
publisher ROYAL SOC CHEMISTRY
issn 1359-7345
year published 2014
volume 50
issue 57
beginning page 7621
ending page 7624
digital object identifier (doi) 10.1039/c4cc02085e
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000338234000012
link 24889410
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journal impact factor 5.996
5 year journal impact factor 5.818
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