Pyrolyzed chitosan-based materials for CO2/CH4 separation

resumo

Chitosan is a biopolymer obtained by deacetylation of chitin extracted from sub-products of the food industry and it is rich in nitrogen content. Pyrolyzed chitosan- and chitosan-periodic mesoporous organosilica (PMO)-based porous materials with different pore structures and chemical features are prepared using different dry methods and ensuing pyrolysis at 800 degrees C, for application in the CO2/CH4 adsorption/separation. The highest CO2 adsorption capacity (1.37 mol.kg(-1) at 100 kPa; 1.9 mol.kg(-1) at 500 kPa) and the best selectivity for CO2/CH4 separation (95 at 500 kPa) is obtained using 1.5% (m/v) of chitosan solution dried under supercritical CO2. This material combines a good CO2 adsorption capacity with one of the highest selectivities for CO2/CH4 separation of the literature, arising as a promising alternative adsorbent for natural gas or biogas upgrading at reduced cost. The presence of high nitrogen content together with pores of diameter around 2 nm leads to an increase of the CO2 adsorption capacity. In the case of chitosan-PMO-based materials, the activation step using both acid and crushing methods is crucial to increase the CO2 adsorbed amount. Here, the highest CO2 adsorption capacity and the highest selectivity are obtained by the chitosan-PMO crushed adsorbent and the chitosan-PMO material activated with sulfuric acid, respectively. These observations indicate the importance of the controlled attack of the material surface to enhance the diffusion of the target gases within the adsorbent, avoiding the adsorption of other species.

palavras-chave

PERIODIC MESOPOROUS ORGANOSILICAS; CARBON-DIOXIDE UTILIZATION; ACTIVATED CARBON; ADSORPTION SEPARATION; POROUS MATERIALS; CO2 SEPARATION; ORGANIC GROUPS; CH4; SILICA; GAS

categoria

Engineering

autores

Lourenco, MAO; Nunes, C; Gomes, JRB; Pires, J; Pinto, ML; Ferreira, P

Grupos

G1 - Materiais Porosos e Nanossistemas
G2 - Materiais Fotónicos, Eletrónicos e Magnéticos
G4 - Materiais Renováveis e Economia Circular
G6 - Materiais Virtuais e Inteligência Artificial

Projectos

Nanoporous materials as multiple therapeutic agents (IF/00993/2012/CP0172/CT0013)

SGH : Smart Green Homes (Smart Green Homes)

agradecimentos

This work was developed within the scope of the projects CICECOAveiro Institute of Materials (Ref. FCT-UID/CTM/50011/2019), financed by national funds through the FCT/MCTES; CERENA (Ref. FCTUID/ECI/04028/2019); IF/00993/2012/CP0172/CT0013 and CQB (Ref. FCT UID/MULTI/00612/2013) and in part, in the scope of the Smart Green Homes Project POCI-01-0247-FEDER-007678, a co-promotion between Bosch Termotecnologia S.A. and the University of Aveiro. These projects are financed by Portugal 2020 under the Competitiveness and Internationalization Operational Program and by the European Regional Development Fund (FEDER). The authors are thankful to Carlos M. Silva and Marcelo M.R. Melo for the help in drying the chitosan-based spheres with supercritical CO2, to Rosana Pinto for the determination of N2-sorption isotherms and to Fundacao para a Ciencia e a Tecnologia (FCT) for the Investigator FCT program (PF, MLP and JRBG) and the grant ref. SFRH/BD/80883/2011 (MAOL) and SFRH/BPD/100627/2014 (CN).