Ultrasonic synthesis of Oct. trans-Br2Cu(N boolean AND N)(2) Jahn-Teller distortion complex: XRD-properties, solvatochromism, thermal, kinetic and DNA-binding evaluations


Under mode of ultrasonic vibration, the neutral octahedral mononuclear [trans-CuBr2(N boolean AND N)(2)]center dot 3H2O complex with N boolean AND N = 2,2-dimethylpropane-1,3-diamine was obtained. The structure of the desired complex was characterized by UV-Vis. spectroscopy, FT-IR, EDX, MS, SEM, TG/DTA and CHN-analysis. The octahedral-structure of the desired Cu(II) complex was proven via XRD single-crystal diffraction and its molecular interactions were computed by Hirschfeld surface analysis. Alcohol (as solvent) and short ultrasonic vibration dose period played a critical role in sonochemistry synthesis of octahedral neutral trans-CuBr2(N boolean AND N)(2) complex instead of trigonal bipyramidal monocation [CuBr(N boolean AND N)(2)]Br one. Due to the Jahn-Teller effect, the complex exhibited a trans bonds elongation along Br-Cu-Br axis originating a distorted-octahedral Cu(II), as revealed by the XRD measurements (Br-Cu = 3.04 angstrom). Therefore, the Solvatochromic behavior of the complex was successfully performed since the trans di-bromide ions are loosely coordinated to Cu(II) center, the change in complex solutions colors by using different solvents which can be detected even by naked-eye supported atypical Jahn-Teller elongation effect formation. TG/DTA and Flynn Wall Ozawa (FWO) isoconversional kinetic methods were applied for the complex to figure out the thermal behavior, kinetic of the ligands de-structured and estimate its Ea/alpha relation. The complex binding mode to the CT-DNA was examined by UV-vis. spectroscopic, melting curve, CV and viscosity tests. The complex exhibited very strong DNA binding via an intercalation mode of coordination with K-b = 6.5 x 10(5) value.




Acoustics; Chemistry


Warad, I; Musameh, S; Sawafta, A; Brandao, P; Tavares, CJ; Zarrouk, A; Arnereih, S; Al Ali, A; Shariah, R

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