resumo
ScPO4:0.1%Eu3+ sintered materials were found to generate orange-red persistent emission following exposure to X-rays. A set of thermoluminescence techniques and isothermal decay measurements were used to study the mechanisms of the carriers' trapping and detrapping processes. The two main TL peaks at around 90 degrees C (363 K) and 160 degrees C (433 K) were found to result from so-called continuous distribution of trap depths. Room temperature fading proved that the persistent luminescence was connected with the strong TL peak at similar to 90 degrees C (363 K). The persistent emission kinetics was characterized by a linear dependence of I-1(t). This was consistent with the continuous distribution of trap energies observed in the material. The main persistent emission components were located around 590, 620, and 720 nm. The most significant contribution was from the first and the third of them, resulting from the D-5(0) -> F-7(1) and D-5(0) -> F-7(4) transitions, respectively. (C) 2019 Elsevier B.V. All rights reserved.
palavras-chave
ISSUE INTRODUCTION PERSISTENT; MECHANISM; ENERGY; EU2+; THERMOLUMINESCENCE; PEROVSKITE; RESOLUTION; PHOSPHORS; EU3+
categoria
Chemistry; Materials Science; Metallurgy & Metallurgical Engineering
autores
Jedon, J; Zeler, J; Zych, E
Grupos
agradecimentos
This research was partially supported by the Polish National Science Center (NCN) under grant number UMO-2015/19/N/ST5/00784. E.Z. acknowledges support from the Polish National Agency for Academic Exchange NAWA under project #PPN/BEK/2018/1/00333/DEC/1.