Vanadoborates: cluster-based architectures, preparation and properties
authors Liu, X; Zhou, J; Amarante, TR; Paz, FAA; Fu, LS
nationality International
journal DALTON TRANSACTIONS
keywords NONLINEAR-OPTICAL CRYSTAL; FRAMEWORK COPPER BOROVANADATE; GROUP OXIDE CLUSTER; HYDROTHERMAL SYNTHESIS; STRUCTURAL-CHARACTERIZATION; VANADIUM BOROPHOSPHATE; POLYOXOVANADIUM BORATE; PROTON CONDUCTION; OXIDATION; CONSTRUCTION
abstract Crystalline polyoxovanadates (POVs) are a subclass of polyoxometalates with significance in chemical, physical and materials sciences. Recent studies revealed that the condensation of vanadate and borate fragments may yield a whole new class of POVs. These novel vanadoborates are typically prepared by high-temperature solid-state, boric acid flux or low-temperature hydrothermal techniques. The different connections of [VOx] (x = 4, 5, 6) and [BOx] (x = 3, 4) polyhedral units ultimately result in a fascinating variety of vanadoborate anionic clusters, which can be at the genesis of a myriad of one-dimensional (1-D), two-dimensional (2-D) and three-dimensional (3-D) polymeric architectures by way of either self-condensation or by forming covalent bonds with other metal ions or unsaturated metal complexes. This review summarizes, in a systematic structural approach, the most striking advances in the syntheses, structural features, and some properties of crystalline vanadoborates based on different [VxBy] and [VxByPz] clusters. It intends to provide meaningful and helpful guidance for the future preparation of new and functional vanadoborates.
publisher ROYAL SOC CHEMISTRY
issn 1477-9226
isbn 1477-9234
year published 2021
volume 50
issue 5
beginning page 1550
ending page 1568
digital object identifier (doi) 10.1039/d0dt03820b
web of science category 19
subject category Chemistry, Inorganic & Nuclear
unique article identifier WOS:000616337100002
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journal analysis (jcr 2019):
journal impact factor 4.174
5 year journal impact factor 3.812
category normalized journal impact factor percentile 90
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