Photodegradation of Aquaculture Antibiotics Using Carbon Dots-TiO2 Nanocomposites


In this work, carbon dots (CD) were synthesized and coupled to titanium dioxide (TiO2) to improve the photodegradation of antibiotics in aquaculture effluents under solar irradiation. Oxolinic acid (OXA) and sulfadiazine (SDZ), which are widely used in aquaculture, were used as target antibiotics. To prepare nanocomposites of CD containing TiO2, two modes were used: in-situ (CD@TiO2) and ex-situ (CD/TiO2). For CD synthesis, citric acid and glycerol were used, while for TiO2 synthesis, titanium butoxide was the precursor. In ultrapure water (UW), CD@TiO2 and CD/TiO2 showed the largest photocatalytic effect for SDZ and OXA, respectively. Compared with their absence, the presence of CD@TiO2 increased the photodegradation of SDZ from 23 to 97% (after 4 h irradiation), whereas CD/TiO2 increased the OXA photodegradation from 22 to 59% (after 1 h irradiation). Meanwhile, in synthetic sea salts (SSS, 30 parts per thousand, simulating marine aquaculture effluents), CD@TiO2 allowed for the reduction of SDZ's half-life time (t(1/2)) from 14.5 +/- 0.7 h (in absence of photocatalyst) to 0.38 +/- 0.04 h. Concerning OXA in SSS, the t(1/2) remained the same either in the absence of a photocatalyst or in the presence of CD/TiO2 (3.5 +/- 0.3 h and 3.9 +/- 0.4 h, respectively). Overall, this study provided novel perspectives on the use of eco-friendly CD-TiO2 nanocomposites for the removal of antibiotics from aquaculture effluents using solar radiation.




Environmental Sciences; Toxicology


Louros, VL; Ferreira, LM; Silva, VG; Silva, CP; Martins, MA; Otero, M; Esteves, VI; Lima, DLD

nossos autores


This work was funded by FEDER through CENTRO 2020, and by national funds through Fundacao para a Ciencia e a Tecnologia, I.P. (FCT), within the research project REM-AQUA (PTDC/ASP-PES/29021/2017). Diana Lima was funded by national funds (OE), through FCT, in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of the article 23, of the Decree-Law 57/2016, of 29 August, changed by Law 57/2017, of 19 July. Marta Otero and Valentina Silva are thankful for the support of the FCT Investigator Program (IF/00314/2015). Moreover, thanks are due for the financial support to CESAM (UIDB/50017/2020+UIDP/50017/2020) and to FCT/MCTES through national funds.

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