The first dinuclear zinc(II) dithiocarbarnate complex with butyl substituent groups
authors Paz, FAA; Neves, MC; Trindade, T; Klinowski, J
nationality International
journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords SINGLE-MOLECULE PRECURSORS; CRYSTAL-STRUCTURE; REDETERMINATION; CDS
abstract The crystal structure of the title compound, bis(mu-N,N-dibutyldithiocarbamato-kappa(2)S:S')bis[(N,N-dibutyldithio-carba\-forcelb]mato-kappa(2)S,S')zinc(II)], [Zn-2(C9H18NS2)(4)], has been determined at 180 K. The structure contains two crystallographically unique Zn2+ metal centres, showing almost identical slightly distorted tetrahedral coordination environments, and forming a dinuclear complex with two skew-bridging syn-N,N-dibutyldithiocarbamate ligands. Two other dithiocarbamate ligands are connected to the Zn2+ centres in a syn,syn-chelate coordination mode.
publisher BLACKWELL MUNKSGAARD
issn 1600-5368
year published 2003
volume 59
beginning page M1067
ending page M1069
digital object identifier (doi) 10.1107/S160053680302419X
web of science category Crystallography
subject category Crystallography
unique article identifier WOS:000186318900048

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