The first dinuclear zinc(II) dithiocarbarnate complex with butyl substituent groups

authors	Paz, FAA; Neves, MC; Trindade, T; Klinowski, J
nationality	International
journal	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords	SINGLE-MOLECULE PRECURSORS; CRYSTAL-STRUCTURE; REDETERMINATION; CDS
abstract	The crystal structure of the title compound, bis(mu-N,N-dibutyldithiocarbamato-kappa(2)S:S')bis[(N,N-dibutyldithio-carba\-forcelb]mato-kappa(2)S,S')zinc(II)], [Zn-2(C9H18NS2)(4)], has been determined at 180 K. The structure contains two crystallographically unique Zn2+ metal centres, showing almost identical slightly distorted tetrahedral coordination environments, and forming a dinuclear complex with two skew-bridging syn-N,N-dibutyldithiocarbamate ligands. Two other dithiocarbamate ligands are connected to the Zn2+ centres in a syn,syn-chelate coordination mode.
publisher	BLACKWELL MUNKSGAARD
issn	1600-5368
year published	2003
volume	59
beginning page	M1067
ending page	M1069
digital object identifier (doi)	10.1107/S160053680302419X
web of science category	Crystallography
subject category	Crystallography
unique article identifier	WOS:000186318900048