A novel cobalt(II)-molybdenum(V) phosphate organic-inorganic hybrid polymer
authors Shi, FN; Paz, FAA; Girginova, PI; Nogueira, HIS; Rocha, J; Amaral, VS; Klinowski, J; Trindade, T
nationality International
journal JOURNAL OF SOLID STATE CHEMISTRY
author keywords hybrid material; molybdenum phosphate; polyoxometalates; magnetochemistry
keywords MOLECULAR MAGNETIC-MATERIALS; COBALT-MOLYBDENUM PHOSPHATE; CENTER-DOT 4H(2)O; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; COORDINATION POLYMER; IRON MOLYBDOPHOSPHATE; WEAK FERROMAGNET; OPEN-FRAMEWORK; TRIMESIC ACID
abstract A new organic-inorganic hybrid cobalt(II)-molybdenum(V) phosphate polymer incorporating piperazine (pip). (H(2)pip)(3)[Co3Mo12O24(OH)(6)(PO4)(8)(H(1.5)pip)(4)]center dot 5(H2O), was prepared under hydrothermal conditions. As revealed by single-crystal X-ray diffraction studies. the material is modular. built front a secondary building block composed of two anionic hexameric polyoxomolybdophosphate [Mo6O12(OH)(3)(PO4)(4)](9-) moieties, bridged by a central octahedral Co2+ centre. The sandwich-type dimers are connected via tetrahedral Co2+ metal centres, forming, an infinite one-dimensional polymer. The compound constitutes the first example of a reduced sandwich-type cobalt-molybdenum phosphate in which the organic moiety (pip) is effectively coordinated to the inorganic backbone of the polymer, in this case via the tetrahedrally coordinated Co2+ centres. The magnetic behaviour Of this material was investigated in the temperature range 4-298 K. (C) 2006 Elsevier Inc. All rights reserved.
publisher ACADEMIC PRESS INC ELSEVIER SCIENCE
issn 0022-4596
year published 2006
volume 179
issue 5
beginning page 1497
ending page 1505
digital object identifier (doi) 10.1016/j.jssc.2006.02.001
web of science category Chemistry, Inorganic & Nuclear; Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000237528900031
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journal impact factor 2.726
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