resumo
The laser floating zone technique was used to grow large 2Al(2)O(3)-SiO2 mullite fibres (up to 1.6 mm in diameter and 40 mm in length). The fibres grown at 10 mm/h are single crystalline in nature, while those pulled at higher rates (40 and 100 mm/h) are polycrystalline with a cellular microstructure. The crystals are highly [0 0 1] textured with respect to the fibre axis, as determined by X-ray diffraction analysis. The Raman spectra taken at different orientations corroborate the strong anisotropy observed by X-ray and SEM on both single crystalline and textured polycrystalline samples. Four point bending tests and ultramicroindentation Vickers experiments were performed at room temperature in order to characterize the mechanical properties. The presence of lamellar inclusions in the single crystalline fibres decreases the flexural strength (431 MPa) and the fracture toughness (1.2 MPa.m(1/2)) compared to the polycrystalline ones (631 MPa and 1.6 MPa.m(1/2)). However, the absence of grain boundaries in the single crystals leads to higher ultramicrohardness (H-v = 15.6 GPa) and Young's modulus (E = 170 GPa) than those of the polycrystalline fibres (14.2 and 145 GPa), where a glassy intergranular phase exists. (c) 2010 Elsevier Ltd. All rights reserved.
palavras-chave
INTERNAL-CRYSTALLIZATION METHOD; CRYSTALS; MICROHARDNESS; MICROSTRUCTURE; 2/1-MULLITE; OXIDE
categoria
Materials Science
autores
Carvalho, RG; Fernandes, AJS; Oliveira, FJ; Alves, E; Franco, N; Louro, C; Silva, RF; Costa, FM
nossos autores
Filipe José Alves de Oliveira
Investigador Principal
Rui Ramos Ferreira e Silva
Professor associadoagradecimentos
The authors acknowledge FCT for the financial funding from PTDC/CTM/66195/2006 project.