Synthesis, magnetic and Mossbauer studies of mechanically alloyed Fe0.63Si0.37 a alloys

resumo

Elemental powder mixtures of Fe and Si were mechanically alloyed with a ball-mill. Mossbauer spectroscopy and X-ray diffraction were used to characterise the microstructural changes of these mixtures which are induced by high-energy ball-milling. Mossbauer spectra are discussed in terms of two main spectral components (corresponding to FeSi alloy and alpha-Fe) and the time dependence of the alloy formation follows a Johnson-Mehl type law. Calorimetry measurements show that the formed alloy is stable up to 800 degrees C as no crystallisation or phase transformation peaks are observed. From X-ray diffraction, a crystallite size of 9 nm is obtained. Magnetic measurements at low temperature were carried out on the final alloy and the saturation magnetic moment at 4.2K is 0.44 mu(B)/Fe.

palavras-chave

AMORPHOUS ALLOYS; FE-SI; SPECTRA

categoria

Materials Science

autores

Costa, BFO; Amaral, VS; Le Caer, G

nossos autores

Partilhe este projeto

Publicações similares

Usamos cookies para atividades de marketing e para lhe oferecer uma melhor experiência de navegação. Ao clicar em “Aceitar Cookies” você concorda com nossa política de cookies. Leia sobre como usamos cookies clicando em "Política de Privacidade e Cookies".