abstract
Polymer based composites containing metal nanoparticles are shown to provide new substrates for SERS detection and simultaneously enable the development of new tools for molecular sensing. A very important aspect on the use of hybrid materials relates to the observation of synergistic effects that result from the use of distinct components such as a polymer and metal nanoparticles. We report here the preparation of new SERS substrates made from blends of colloidal Au (nanospheres and nanorods) and PtBA (poly(t-butylacrylate)). The observed SERS enhancement depends on the characteristics of the obtained hybrid material. When compared to the starting Au colloids, the Au/PtBA nanocomposites led to SERS spectra with more intense bands, using 2,2'-dithiodipyridine as molecular probe. The origin of the stronger Raman signal in this case, is possibly due to a combination of events related to the nanocomposite characteristics, including the formation of Au assemblies at the polymer surface due to particle clustering, and the absorption increase in a spectral region closer to the laser excitation wavelength. The strategy described here is a low-cost process with potential for the up-scale fabrication of SERS substrates, namely by using other types of nanocomposites. (C) 2013 Elsevier B.V. All rights reserved.
keywords
ENHANCED RAMAN-SCATTERING; SURFACE-PLASMON RESONANCE; SILVER NANOPARTICLES; OPTICAL-PROPERTIES; NANOFIBER MATRIX; ASPECT RATIO; SHAPE; SEED; 2,2'-DITHIODIPYRIDINE; NANOCOMPOSITES
subject category
Spectroscopy
authors
Fateixa, S; Pinheiro, PC; Nogueira, HIS; Trindade, T
our authors
acknowledgements
S. Fateixa thanks Fundacao para a Ciencia e Tecnologia (FCT/FEDER) for the Grant SFRH/BD/66460/2009. The authors acknowledge FCT (Pest-C/CTM/LA0011/2011), FSE and POPH for funding.