abstract
The tribological response of multilayer micro/nanocrystalline diamond coatings grown by the hot filament CVD technique is investigated. These multigrade systems were tailored to comprise a starting microcrystalline diamond (MCD) layer with high adhesion to a silicon nitride (Si3N4) ceramic substrate, and a top nanocrystalline diamond (NCD) layer with reduced surface roughness. Tribological tests were carried out with a reciprocating sliding configuration without lubrication. Such composite coatings exhibit a superior critical load before delamination (130-200 N), when compared to the mono- (60-100 N) and bilayer coatings (110 N), considering similar to 10 mu m thick films. Regarding the friction behaviour, a short-lived initial high friction coefficient was followed by low friction regimes (friction coefficients between 0.02 and 0.09) as a result of the polished surfaces tailored by the tribological solicitation. Very mild to mild wear regimes (wear coefficient values between 4.1 x 10(-8) and 7.7 x 10(-7) min(3) N-1 m(-1)) governed the wear performance of the self-mated multilayer coatings when subjected to high-load short-term tests (60-200 N; 2 h; 86 m) and medium-load endurance tests (60 N; 16 h; 691 m). (C) 2013 Elsevier B.V. All rights reserved.
keywords
CHEMICAL-VAPOR-DEPOSITION; COATED SILICON-NITRIDE; X-RAY-DIFFRACTION; NANOCRYSTALLINE DIAMOND; ADHESION STRENGTH; FILMS; PERFORMANCE; BEHAVIOR; SI3N4; PRETREATMENTS
subject category
Engineering; Materials Science
authors
Salgueiredo, E; Abreu, CS; Amaral, M; Oliveira, FJ; Gomes, JR; Silva, RF
our authors
Filipe José Alves de Oliveira
Principal Researcher
Rui Ramos Ferreira e Silva
Associate ProfessorProjects
acknowledgements
This work was funded by Projects MULTIDIACOAT - PTDC/EME-TME/100689/2008 and Pest-C/CTM/LA0011/2011 from Fundacao para a Ciencia e Tecnologia (FCT, Portugal). E. Salgueiredo and M. Amaral also acknowledge FCT for the Grants SFRH/BD/41757/2007 and SFRH/BPD/26787/2006, respectively. A.J.S. Fernandes from Physics Department of Aveiro University is gratefully acknowledged for the Raman spectroscopy analysis.