Synthesis, characterizations and structure of orthometallated Pt(II) and Pt(IV) complexes: Oxidative addition to C,N,N,O coordinated Pt(II) complexes
authors Pattanayak, P; Parua, SP; Patra, D; Pratihar, JL; Brandao, P; Felix, V; Chattopadhyay, S
nationality International
journal POLYHEDRON
author keywords 2-(arylazo)-1-N-salicylidene phenylamine; Pt(II)/Pt(IV); Orthometallation; Oxidative addition
keywords C-H ACTIVATION; HETEROGENEOUS CATALYSIS; PLATINUM(II) COMPLEXES; VISIBLE-LIGHT; PALLADIUM; REACTIVITY; LIGAND; NANOPARTICLES; REDUCTION; PALLADACYCLES
abstract Reactions of 2-(arylazo)-1-N-salicylidene phenylamine, H2L, 1, [H represents the dissociable protons upon complexation], with K2PtCl4 afforded orthometallated complexes of composition [Pt(L)], 2 where the Pt(II) is coordinated by the tetradentate (C,N,N,O) ligand, L2-. Reaction of the precursor complex [Pt(L)] with I-2 afforded octahedral complexes of composition [PtI2(L)], 3. All the complexes were characterized unequivocally. X-ray crystal structure of [Pt(L-1)] and [Pt I-2(L-1)] have been determined. (C) 2014 Published by Elsevier Ltd.
publisher PERGAMON-ELSEVIER SCIENCE LTD
issn 0277-5387
year published 2014
volume 70
beginning page 1
ending page 5
digital object identifier (doi) 10.1016/j.poly.2013.12.014
web of science category Chemistry, Inorganic & Nuclear; Crystallography
subject category Chemistry; Crystallography
unique article identifier WOS:000332142600001
  ciceco authors
  impact metrics
journal analysis (jcr 2019):
journal impact factor 2.343
5 year journal impact factor 1.894
category normalized journal impact factor percentile 60.363
dimensions (citation analysis):
altmetrics (social interaction):



 


Sponsors

1suponsers_list_ciceco.jpg