Neutral bimetallic rhenium(I)-containing halogen and hydrogen bonding acyclic receptors for anion recognition

abstract

Neutral bimetallic rhenium(I) bis-triazole pyrimidine halogen bonding (XB) and hydrogen bonding (HB) acyclic anion receptors are prepared and H-1 NMR titration investigations reveal the XB receptor exhibits significantly superior anion recognition behaviour. (C) 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

keywords

EFFECTIVE CORE POTENTIALS; BASIS-SETS; MOLECULAR CALCULATIONS; TERMINAL ALKYNES; AQUEOUS-MEDIA; COMPLEXES; ROTAXANE; ELEMENTS; HOSTS; COORDINATION

subject category

Chemistry

authors

Mole, TK; Arter, WE; Marques, I; Felix, V; Beer, PD

our authors

acknowledgements

T.K.M. would like to thank EPSRC for a DTA studentship. IM thanks the FCT (Fundacao para a Ciencia e a Tecnologia) for the PhD scholarship SFRH/BD/87520/2012.

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