authors |
Goncalves, IS; Veiros, LF; Gamelas, CA; Cabrita, C; Calhorda, MJ; Geraldes, CFGC; Green, J; Packham, E; Drew, MGB; Felix, V; Santos, AG; Romao, CC |
nationality |
International |
journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
author keywords |
Molybdenum; Allyl complexes; Mo-95 NMR; DFT calculations; PES spectroscopy |
keywords |
MOLECULAR-ORBITAL METHODS; EXTENDED BASIS-SETS; VALENCE BASIS-SETS; ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA; BRIDGED HETEROBIMETALLIC COMPLEXES; DENSITY-FUNCTIONAL CALCULATIONS; RAY PHOTOELECTRON-SPECTROSCOPY; CONTINUUM SOLVATION MODELS; EFFECTIVE CORE POTENTIALS; TRANSITION-METAL ATOMS |
abstract |
A series of allyl complexes of the general formula [Cp'Mo(eta(3)-C3H5)(CO)(2)], where Cp' = Cp, CpMe, Cp*, Ind, IndMe, IndMe2, Flu, and three tungsten analogues, has been prepared and characterized by H-1, C-13, and Mo-95 NMR, cyclic voltammetry, and the structure of [IndMo(eta(3)-C3H5)(CO)(2)] was determined by Xray single crystal analysis. Two conformers, corresponding to the two extreme orientations of the allyl ligand (endo and exo), have been identified in solution by H-1 and Mo-95 NMR for all the complexes, except for [FluMo(eta(3)-C3F15)(CO)(2)], which only presents an exo conformation in solution. A Mo-95 NMR investigation also shows the influence of electron donor capability of the Cp' ligands on the Mo-95 chemical shifts of the Mo center. He I and He II photoelectron spectra probe the electron richness of the metal center and the electronic structure of the complexes. Cyclic voltammetry studies show one oxidation process, which is only reversible for the Cp derivatives. DFT calculations provided a reliable way to determine ionization energies, and reflected very well the trends of the other properties, from the Mo-95 NMR chemical shifts, to vibration frequencies, and oxidation potentials. (1) 2015 Elsevier BY. All rights reserved. |
publisher |
ELSEVIER SCIENCE SA |
issn |
0022-328X |
year published |
2015 |
volume |
792 |
beginning page |
154 |
ending page |
166 |
digital object identifier (doi) |
10.1016/j.jorganchem.2015.04.001 |
web of science category |
Chemistry, Inorganic & Nuclear; Chemistry, Organic |
subject category |
Chemistry |
unique article identifier |
WOS:000359201500023
|
ciceco authors
impact metrics
journal analysis (jcr 2019):
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journal impact factor |
2.304 |
5 year journal impact factor |
1.963 |
category normalized journal impact factor percentile |
55.965 |
dimensions (citation analysis):
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altmetrics (social interaction):
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