authors |
Amarante, TR; Goncalves, IS; Paz, FAA |
nationality |
International |
journal |
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
author keywords |
crystal structure; 4,4 '-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation; beta-octamolybdate anion; hydrogen-bonding network |
keywords |
COORDINATION POLYMERS; ALCOHOLS; DATABASE; LIGANDS |
abstract |
The asymmetric unit of the title compound, bis[4,4'-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium)] beta-octamolybdate, (C11H18N4)(2)[Mo8O26] or (H(4)mbdpz)(2)[Mo8O26], is composed of an H(4)mbdpz(2+) cation and half of the beta-octamolybdate anion which is completed by inversion symmetry. The organic molecular units are engaged in a series of N-H center dot center dot center dot O hydrogen bonds with neighbouring anions, with N center dot center dot center dot O distances and N-H center dot center dot center dot O angles in the ranges 2.730 (2)-2.941 (2) angstrom and 122-166 degrees, respectively. These interactions lead to the formation of a supramolecular two-dimensional network parallel to the (010) plane. |
publisher |
INT UNION CRYSTALLOGRAPHY |
issn |
2056-9890 |
year published |
2016 |
volume |
72 |
beginning page |
124 |
ending page |
+ |
digital object identifier (doi) |
10.1107/S2056989015024524 |
web of science category |
Crystallography |
subject category |
Crystallography |
unique article identifier |
WOS:000370798100005
|