Tatiana Ribau Amarante

Junior Researcher

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  • Chemistry

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education

Pos-Doc. in Chemistry                                                   First degree in Design
University of Aveiro                                                           University os Aveiro
2014 to present                                                                2011 to present

Doc. in Chemistry
University of Aveiro
2010 to 2013

Master degree in Materials Science and Engineering
University of Aveiro
2007 to 2009

First degree in Chemistry
Universuty of Aveiro
2001 to 2008

High School 
Escola Dr. Joõao Carlos Celestino Gomes, Ílhavo
2001

published papers

2018

  • M. M. Antunes, T. R. Amarante, A. A. Valente, F. A. Almeida Paz, I. S. Gonçalves, M. Pillinger
    A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions. 
    ChemCatChem, 10, 2018, 2782. doi: 10.1002/cctc.201800232

2016

  • P. Neves, T. R. Amarante, A. A. Valente, M. Pillinger, I. S. Gonçalves
    Catalytic Application of an Octamolybdate Salt (H3biim)4[ß-Mo8O26] in Olefin Epoxidation (H2biim = 2,2’-biimidazole).
    Catalysis Letters, 146, 2016, 841-850. doi: 10.1007/s10562-016-1702-0

 

  • T. R. Amarante, P. Neves, A. A. Valente, F. A. Almeida Paz, M. Pillinger, I. S. Gonçalves 
    Metal oxide-triazole as heterogeneous or reaction-induced self-separating catalysts, Journal of Catalysis, 340, 2016, 354-367. doi: 10.1016/j.jcat.2016.06.005

 

  • T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz 
    Crystal structure of an organic-inorganic supramolecular salt based on 4,4’-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cations and the ß-octamolybdate anion, Acta Crystallographic Section E, E72, 2016, 124-127. doi: 10.1107/S2056989015024524

 2015

  • T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz 
    Redetermination of the crystal structure of 3,5-dimethylpyrazolium ß-octamolybdate tetrahydrate, Acta Crystallographic Section E, E71, 2015, m244-m245. 
    doi: 10.1107/S2056989015022823

 

  • T. R. Amarante, M. M. Antunes, A. A. Valente, F. A. Almeida Paz, M. Pillinger, I. S. Gonçalves, Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid, Inorganic Chemistry, 54, 2015, 9690-9703. 
    doi: 10.1021/acs.inorgchem.5b00928

 

  • P. Neves, A. C. Gomes, T. R. Amarante, F. A. Almeida Paz, M. Pillinger, I. S. Goçalves, A. A. Valente, Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidation, Microporous and Mesoporous Materials, 2015, 202, 106-114. 
    doi: 10.1016/j.micromeso.2014.09.046

 2014

  • T. R. Amarante, P. Neves, A. C. Gomes, M. M. Nolasco, P.R.-Claro, A C. Coelho, A. A. Valente, F. A. Almeida Paz, S. Smeets, L. B. McCusker, M. Pillinger, I. S. Gonçalves 
    Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)]n, Inorg. Chem., 2014, 53, 2652–2665. 
    doi: 10.1021/ic403033j

 

  • T. R. Amarante, P. Neves, F. A. Almeida Paz, A. A. Valente, M. Pillinger, I. S. Gonçalves, Investigation of dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivate as catalysts in olefin epoxidation, Dalton Trans., 2014, 43, 6059-6069. doi: 10.1039/c3dt52981a 

 2013

  • T. R. Amarante, A. C. Gomes, P. Neves, F. A. Almeida Paz, A. A. Valente, M. Pillinger, I. S. Gonçalves
    A Dinuclear Oxo-bridge Molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and Catalytic performance for Olefin Epoxidation, Inorg. Chem. Commun., 32, 2013, 59-63. 

 

  • T. R. Amarante, P. Neves, A. A. Valente, F. A. Almeida Paz, A- N. Fitch, M. Pillinger, I. S. Gonçalves
    Hydrothermal Synthesis, Crystal Structure, and Catalytic Potencial of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid, Inorg. Chem., 52, 2013, 4618-4628. doi: 10.1021/ic400248m

 2012

  • S. Figueiredo, A. C. Gomes, P. Neves, T. R. Amarante, F. A. Almeida Paz, R. Soares, A. D. Lopes, A. A. Valente, M. Pillinger, I. S. Gonçalves
    Shynthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation, Inorg. Chem., 51, 2012, 8629-8635. doi: 10.1021/ic301405r

 

  • T. R. Amarante, P. Neves, F. A. Almeida Paz, M. Pillinger, A. A. Valente, I. S. Gonçalves
    A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4’-di-tert-butyl-2,2’-bipyridine)2], displaying the [MoO2(μ-O)2MoO2]0 core, and its use as a catalyst in olefin epoxidation,Inorg. Chem. Commun., 20, 2012, 147-152. doi:10.1016/j.inoche.2012.02.038

 

  • T. R. Amarante, P. Neves, C. Tomé, M. Abrantes, A. A. Valente, F. A. A. Paz, M. Pillinger, and I. S. Gonçalves
    An Octanuclear Molybdenum(VI) Complex Containing Coordinatively Bound 4,4'-di-tert-Butyl-2,2'-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins, Inorg. Chem., 51, 2012,3666-3676. doi: 10.1021/ic202640a

 2011

  • T. R. Amarante, J. A. Fernandes, I. S. Gonçalves, F. A. Almeida Paz
    Tris(4,4'-di-tert-butyl-2,2-bipyridine-κ2N,N')molybdenum(II)(μ6-oxo)-dodecakis(μ2-oxo)-hexaoxohexamolybdate(VI)acetonitriletetrasolvate, Acta Crystallogr., Sect. E: Struct. Rep. Online, E67, 2011, m1828-m1829. doi:10.1107/S1600536811049385

 

  • T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
    Di-tert-butyl-2,2’-dipirydine chloride, Acta Crystallogr., Sect. E: Struct. Rep. Online, E67, 2011, o1903-o1904. doi:10.1107/S1600536811025529

 

  • P. Neves, T. R. Amarante, A. C. Gomes, A. C. Coelho, S. Gago, M. Pillinger, I. S. Gonçalves, C. M. Silva, A. A. Valente
    Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide. Applied Catalysis A: General,2011, 395, 71-77. doi:10.1016/j.apcata.2011.01.029

  2010

  • M. Abrantes, T. R. Amarante, M. M. Antunes, S. Gago, F. A. Almeida Paz, I. Margiolaki, A. E. Rodrigues, M. Pillinger, A. A. Valente, I. S. Gonçalves
    Synthesis, Structural and Catalytic Performance in Olefin Epoxidation of a New Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n, Inorganic Chemistry, 2010, 49, 6865-6873. doi: 10.1021/ic100479a

  

  • T. R. Amarante, Patrícia N., A. C. Coelho, S. Gago, A. A. Valente, F. A. Almeida Paz, M. Pillinger, and I. S. Gonçalves 
    Investigation of molybdenum tetracarbonyl complexes as precursors to MoVI catalysts for the epoxidation of olefins, Organometallics, 2010, 29, 883-892.

 2009

  • I. S. Gonçalves, A. D. Lopes, T. R. Amarante, F. A. Almeida Paz, N. J. O. Silva, M. Pillinger, S. Gago, F. Palácio, E. F. Kühn, C. C. Romão
    Heterometallic Complexes Involving Iron(II) and Rhenium(VII) Centers Connected by u-Oxido Bridges: Synthesis, Structures and Magnetic Properties. Dalton Trans., 2009, 10199-10207.

 

  • T. R. Amarante, F. A. Almeida Paz, S. Gago, I. S. Gonçalves, M. Pillinger, A. E. Rodrigues, M. Abrantes
    Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4'-di-tert-butyl-2,2'-bipyridine)molybdenum(VI). Molecules, 14, 2009, 3610-3620. doi:10.3390/molecules14093610

 

  • T. R. Amarante, S. Figueiredo, A. D. Lopes, I. S. Gonçalves, F. A. Almeida Paz
    4,4'-Di-tert-butyl-2,2'-dipyridyl. Acta Crystallographica Section E: Struture Reports Online, E65, 2009, o2047. doi:10.1107/S1600536809029109

 

  • T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz 
    2-(1H-Pyrazol-3-yl)pyridinium chloride monohydrate. Acta Crystallographica Section E: Structure Reports Online, E65, 2009, o1962-o1963. doi:10.1107/S1600536809028402

 

  • T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
    Mo4(n3-allyl)4Cl2(OH)2(CO)8: the first cubane-type Mo2+ organometallic complex with u3-OH and u3-Cl bridges. Acta Crystallographica Section C: Crystal Structures Comunications, 65, 2009, m168-m170. doi:10.1107/S0108270109009512

 2008

  • T. R. Amarante, A. C. Coelho, J. Klinowski, I. S. Gonçalves, F. A. Almeida Paz
    1-Hydroxy-1,1,3,3,3-pentaphenyldisiloxane, [Si2O(OH)(Ph)5], at 150 K. Acta Crystallographica Section E: Struture Reports Online, E64, 2008, o239-o239. doi:10.1107/S1600536807064987

 

  • A. C. Coelho, T. R. Amarante, J. Klinowski, I. S. Gonçalves, F. A. Almeida Paz
    1-Hydroxy-1,1,3,3,3-pentaphenyl- disiloxane,  [Si2O(OH)(Ph)5] at 100 K. Acta Crystallographica Section E: Structure Reports Online, E64, 2008, o237-o238. doi:10.1107/S1600536807064975

 

project collaborations at

European Synchrotron Radiation Facility (ESRF, Grenoble, France) from:

  • September 25 to 27, 2015, line ID22.

    CH4325: “Robust Photoluminescent Metal-Organic Frameworks for Sensors: Large Pores Induced by Rigid Polyphosphonate Linkers”;

  • September 27 to 29, 2015, line ID22 and BM25b.

    CH4439: “Metal-Organic Frameworks as Proton Conductors for Processing into Fuel Cells”;

 

  • November 3 to 6, 2014, line ID22.

    CH4254: “Functional Large-Pore Lanthanide-Polyphosphonate MOF Materials”;

 

  • February 5 to 9, 2014, line BM01a.

    CH3995: “Bioinorganic and flavone ruthenium complexes designed for targeted antitumoral action”;

 

  • September 4 to 11, 2013, line ID11.

    CH3718: “Bifunctional Lanthanide-Organic Frameworks with Polyphosphonate Organic Linkers”;

    CH3837: “Anion Binding Agents with Adequate Structural Features, for Biomedical, Environmental and Sensing Applications”;

 

 

Diamond Light Source (Oxford, UK) from;

  • January 27 until 30, 2013, line I11.

    EE8234: “Metal-Organic Frameworks with Phosphonate Linkers”.

 

 

Other project collaborations:

  • January 2014 (participation of 25% time)

    RENASCER: “Robust Nanometric Metal-Organic Frameworks for Gas Separation and Light Emission”

computer skills

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Publications

Heterogeneous catalysis with an organic-inorganic hybrid based on MoO3 chains decorated with 2,2 '-biimidazole ligands

Amarante, TR; Neves, P; Paz, FAA; Gomes, AC; Pillinger, M; Valente, AA; Goncalves, IS
2021, CATALYSIS SCIENCE & TECHNOLOGY, 11, 6, 2214-2228.
ISBN: 2044-4761

Vanadoborates: cluster-based architectures, preparation and properties

Liu, X; Zhou, J; Amarante, TR; Paz, FAA; Fu, LS
2021, DALTON TRANSACTIONS, 50, 5, 1550-1568.
ISBN: 1477-9234

A Copper(I)-Thioarsenate(III) Inorganic Framework Directed by [Ni(en)(3)](2+)

Liu, X; Zhou, J; Huang, L; Xiao, HP; Amarante, TR; Paz, FAA; Xiang, B; Fu, LS
2021, INORGANIC CHEMISTRY, 60, 9, 6813-6819.
ISBN: 1520-510X

A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin Epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2019, MOLECULES, 24, 1.

A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions

Antunes, MM; Amarante, TR; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 13, 2782-2791.

Catalytic Application of an Octamolybdate Salt (H(3)biim)(4)[beta-Mo8O26] in Olefin Epoxidation (H(2)biim=2,2'-biimidazole)

Neves, P; Amarante, TR; Valente, AA; Pillinger, M; Goncalves, IS
2016, CATALYSIS LETTERS, 146, 4, 841-850.

Crystal structure of an organic-inorganic supramolecular salt based on a 4,4 '-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a beta-octamolybdate anion

Amarante, TR; Goncalves, IS; Paz, FAA
2016, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 72, 124-+.

Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2016, JOURNAL OF CATALYSIS, 340, 354-367.

Redetermination of the crystal structure of 3,5-dimethylpyrazolium beta-octamolybdate tetrahydrate

Amarante, TR; Goncalves, IS; Paz, FAA
2015, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 71, M244-+.

Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid

Amarante, TR; Antunes, MM; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 20, 9690-9703.

Novos Materiais Híbridos de Oxomolibdénio(VI)

Tatiana Ribau Amarante
2013, supervised by Isabel Maria de Sousa Gonçalves.

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