Luminescent Carrageenan Hydrogels Containing Lanthanopolyoxometalates

abstract

In this research, we investigated the use of lanthanopolyoxometalates {LnPOM, K-9[Ln(W5O18)(2)], Ln = Eu, Tb} as luminophores in thermosensitive polysaccharides such as carrageenan hydrogels. We demonstrate that the LnPOM species still show the characteristic photoluminescence bands of the Ln(III) ion when incorporated in the gel matrix. Moreover, the strength of the carrageenan hydrogels increases by increasing the amount of LnPOM added because of the effect of K+ ions as cross-linkers, but without compromising the photoluminescent behaviour. Nanoscale homogeneity is crucial regarding applications of hydrogels responsive to external stimuli. This research shows that the final LnPOM-loaded hydrogels are homogeneous as a consequence of the diffusion behaviour of the luminophore species within the gel network. Therefore, we anticipate that the association of carrageenan hydrogels to luminescent lanthanopolyoxometalates might be of great relevance for optical devices and in particular for bioimaging techniques.

keywords

IN-SITU SYNTHESIS; ANTITUMORAL ACTIVITY; HYBRID MATERIALS; QUANTUM DOTS; LANTHANIDE; COMPLEXES; GELS; NANOPARTICLES; WATER; PHOTOLUMINESCENT

subject category

Chemistry

authors

Fateixa, S; Carvalho, RS; Daniel-da-Silva, AL; Nogueira, HIS; Trindade, T

our authors

acknowledgements

This work was financed by national funds through the Fundacao para a Ciencia e a Tecnologia (FCT)/Ministerio da Educacao (MEC) within the scope of the project CICECO-Aveiro Institute of Materials POCI-01-0145-FEDER-007679 (FCT Ref. UID/CTM/50011/2013), and, when appropriate, cofinanced by Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement. S. F. thanks the Fundacao para a Ciencia e Tecnologia (FCT) for the grant SFRH/BPD/93547/2013. A. L. D.-d.-S. acknowledges the Fundacao para a Ciencia e Tecnologia (FCT) for funding (IF-2014).

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