Dibenzoanthradiquinone Building Blocks for the Synthesis of Nitrogenated Polycyclic Aromatic Hydrocarbons

abstract

A straightforward method for the synthesis of two dibenzo[a,h]-anthracene-5,6,12,13-diquinone building blocks is reported. To showcase their usefulness, a series of dibenzo[a,h]-anthracene nitrogenated derivatives have been synthesized that show different optoelectronic, redox, and charge transport properties, illustrating their potential as organic semiconductors.

keywords

EFFICIENT OXIDANT; QUINOXALINES; CORONENE

subject category

Chemistry

authors

Martinez, JI; Mora-Fuentes, JP; Carini, M; Saeki, A; Melle-Franco, M; Mateo-Alonso, A

our authors

acknowledgements

We are grateful to the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country (Grupo de Investigacion GIU17/054), Gobierno de Espana (Ministerio de Economia y Competitividad CTQ2016-77970-R), Gobierno Vasco (PIBA 2019-09 and BERC programme) and acknowledge technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). This project has received funding from the European Union's Horizon 2020 research and innovation programme under Grant Agreement No. 664878. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant Agreement No. 722951). Support through the project IF/00894/2015 and within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 and UIDP/50011/2020, financed by national funds through the Portuguese Foundation for Science and Technology/MCTES is gratefully acknowledged.

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