X-ray structurally characterized Mo (VI), Fe (III) and Cu (II) complexes of amide-imine conjugate: (bio)catalytic and histidine recognition studies

authors	Ta, S; Ghosh, M; Salam, N; Das, J; Islam, M; Brandao, P; Felix, V; Sanmartin, J; Das, D
nationality	International
journal	APPLIED ORGANOMETALLIC CHEMISTRY
author keywords	amide imine conjugate; catalysis; Fe (III) and cu (II) complexes; histidine recognition; Mo (VI)
keywords	2,6-DIACETYLPYRIDINE DAP HYDRAZONES; MESO-EPOXIDES; FLUORESCENT SENSOR; AMINO-ACIDS; RICH GLYCOPROTEIN; OXIDATIVE STRESS; AROMATIC-AMINES; ENANTIOSELECTIVE RECOGNITION; CHEMOSENSING ENSEMBLE; ASYMMETRIC AMINOLYSIS
abstract	An amide-imine conjugate, (E)-N '-((2-hydroxybenzen-1-yl) methylene)-4-methylbenzohydrazide (H2LPTASAL), derived from 4-methyl-benzoic acid hydrazide (PTA) and 2-hydroxybenzaldehyde is used to prepare Mo (VI), Cu (II) and Fe (III) complexes. The X-ray structurally characterized complexes have been explored as catalyst for amine assisted asymmetric ring opening (ARO) of epoxide, carbon-heteroatom cross-coupling and ethyl benzene oxidation. In addition, their catecholase like activities have thoroughly been investigated. Moreover, the Cu (II) complex selectively recognizes histidine by fluorescence spectroscopy.
publisher	WILEY
issn	0268-2605
isbn	1099-0739
year published	2020
volume	34
issue	10
digital object identifier (doi)	10.1002/aoc.5823
web of science category	Chemistry, Applied; Chemistry, Inorganic & Nuclear
subject category	Chemistry
unique article identifier	WOS:000546075600001