An integrated characterisation of incineration bottom ashes towards sustainable application: Physicochemical, ecotoxicological, and mechanical properties

abstract

Environmental protection is a central concern regarding municipal solid waste incineration bottom ash (IBA) management, but the assessment of waste Hazardous Property HP14 (ecotoxicity) is still under debate. Civil engineering applications may be a suitable management strategy. This work aimed at evaluating IBA regarding mechanical behaviour and environmental hazardous potential, including a biotest battery for ecotoxicity assessment (comprising miniaturised tests), to explore its potential for safe utilization. Physical, chemical, ecotoxicological (Aliivibrio fischeri, Raphidocelis subcapitata, Lemna minor, Daphnia magna, Lepidium sativum), and mechanical (one-dimensional compressibility, shear strength) analyses were performed. The low leaching for potentially toxic metals and ions complied with European Union (EU) limit values for non-hazardous waste landfills. No relevant ecotoxicological effects were found. The biotest battery seems suitable for ecotoxicological assessment in the aquatic ecosystem, providing wide information on waste impact on different trophic/functional levels and chemical uptake routes, simultaneously involving short-duration tests and reduced amounts of waste.

keywords

SOLID-WASTE INCINERATION; FLY-ASH; HEAVY-METALS; BEHAVIOR; IDENTIFICATION; CONSTRUCTIONS; PHYTOTOXICITY; LEACHABILITY; GERMINATION; FRACTIONS

subject category

Engineering; Environmental Sciences & Ecology

authors

Bandarra, BS; Mesquita, C; Passos, H; Martins, RC; Coelho, PALF; Pereira, JL; Quina, MJ

our authors

acknowledgements

Thanks are due to FCT/MCTES for their financial support to CIEPQPF (UIDB/00102/2020) , CESAM (UIDP/50017/2020 + UIDB/50017/2020 + LA/P/0094/2020), and CICECO (UIDB/50011/2020, UIDP/50011/2020 & LA/P/0006/2020) through national funds. B.S.B. is the recipient of an individual research grant by the FCT/MCTES with the reference SFRH/BD/147920/2019, through national funds and ESF (European Social Fund) . H. Passos acknowledges FCT - Fundacao para a Ciencia e a Tecnologia, I.P. for the researcher contract CEECIND/00831/2017 under the Scientific Employment Stimulus-Individual Call 2017.

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