Ion-exchange voltammetry with nafion/poly(sodium 4-styrenesulfonate) mixed coatings on mercury film electrodes: Characterization studies and application to the determination of trace metals

abstract

This work aimed to produce improved polymer coatings for the modification of thin mercury film electrodes (TMFEs). The goal is to obtain sensitive, reproducible, mechanically stable and antifouling devices suitable for the determination of trace metal cations in complex media. Therefore, novel mixed coatings of two sulfonated cation-exchange polymers of dissimilar characteristics - Nafion (NA) and poly(sodium 4-styrenesulfonate) (PSS) swere produced by solvent evaporation onto glassy carbon electrodes. The effect of the mass ratio (NA: PSS) on the film morphology was studied by scanning electron microscopy, revealing the formation of biphasic polymer systems, where PSS bead-shaped clusters appeared randomly dispersed into a uniform and compact NA environment. The permselectivity/ion-exchange features of the mixed films onto glassy carbon were evaluated using cathecol, urate, and dopamine. To allow trace metal analysis, thin mercury films were plated through the NA/PSS coatings, being the reproducibility and ion-exchange features of the mixed coatings-TMFE evaluated using lead ions. The best NA/PSS coating was found for the mass ratio of 5.3. Analytical performance of the NA/PSS-TMFE yielded a detection limit of 5.5 nM (3 sigma), and the application of this modified electrode to an untreated polluted estuarine water sample produced significant improvements in the quality of the signal compared with that for a bare TMFE.

keywords

GLASSY-CARBON ELECTRODES; ANODIC-STRIPPING VOLTAMMETRY; POLYMER-MODIFIED ELECTRODES; IN-SITU; SENSORS; LEAD; ADSORPTION; SURFACES; CADMIUM; DENSITY

subject category

Chemistry; Materials Science

authors

Rocha, LS; Pinheiro, JP; Carapuca, HM

Groups

Share this project:

Related Publications

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".