Trimethyl 2,2 ',2 ''-[1,3,5-triazine-2,4,6triyltris(azanediyl)]triacetate
authors Vilela, SMF; Paz, FAA; Tome, JPC; Bermudez, VD; Cavaleiro, JAS; Rocha, J
nationality International
journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords FRAMEWORKS; LIGAND
abstract The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N-H center dot center dot center dot O hydrogen bonds into supramolecular double tapes running parallel to the [010] crystallographic direction. The close packing of supramolecular tapes is mediated by geometrical reasons in tandem with a number of weaker N-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen-bonding interactions.
publisher WILEY-BLACKWELL
issn 1600-5368
year published 2010
volume 66
beginning page O3243
ending page U1308
digital object identifier (doi) 10.1107/S1600536810047604
web of science category Crystallography
subject category Crystallography
unique article identifier WOS:000285090900116

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