Deposition of silver nanoparticles onto human serum albumin-functionalised multi-walled carbon nanotubes

abstract

To facilitate the design of carbon nanotube (CNT)-based hybrid materials, a strategic approach for nanotube dispersion in aqueous media is required. This means that the reactants must exhibit certain selectivity towards both the nanotubes and the solvent medium. The main goal of this study was to prepare new bionanomaterials based on human serum albumin (HSA) and multi-walled CNTs (MWCNTs), under mild conditions and without covalent modification of the nanotubes. Silver nanoparticles (AgNPs) of a controlled particle size, about 2-nm diameter, were prepared and directly deposited onto the HSA-functionalised MWCNTs. The characterisation of AgNP/HSA-MWCNT hybrids prepared was carried out by scanning tunneling microscopy and transmission electron microscopy (TEM). The presence of the AgNPs was corroborated by elemental chemical analysis using TEM-coupled energy-dispersive X-ray spectroscopy. The density of AgNPs coverage is discussed as a function of HSA concentration, the strength of the reducing agent, and the nature of protein employed (HSA vs. bovine serum albumin and rotavirus nucleocapsid protein VP6). (c) 2012 Canadian Society for Chemical Engineering

keywords

AG NANOPARTICLES; DECORATION; PROTEIN; OXIDATION; ELECTRODE

subject category

Engineering

authors

Rodriguez-Galvan, A; Contreras-Torres, FF; Basiuk, EV; Heredia, A; Basiuk, VA

Groups

acknowledgements

Financial support from the National Autonomous University of Mexico (grant DGAPA-IN103009), from the National Council of Science and Technology of Mexico (CONACYT, grant 127299), and from the Institute of Science and Technology of the Federal District Government (ICyTDF, grant 333/2009) is greatly appreciated. Flavio F. Contreras-Torres acknowledges support from ICyTDF for a postdoctoral fellowship (contract ICYTDF/SRI/2/2011). Andres Rodriguez-Galvan thanks to CONACyT for a PhD fellowship. The authors also thank to Dr. Laura A. Palomares (IBT-UNAM) who kindly provided VP6 protein, Dr. Victor Meza-Laguna for assistance in TEM, and Mr. Alexander Ortiz for grammar editing.

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