abstract
Novel trifunctional monomers based on renewable resources were prepared and subsequently polymerized via the Diels-Alder (DA) polycondensation between furan and maleimide complementary moieties. Three basic approaches were considered for these nonlinear DA polycondensations, namely the use of (i) a bisfuran monomer in combination with a trismaleimide (A2 + B3 system) and (ii) a trisfuran monomer in conjunction with a bismaleimide (A3 + B2 system) leading to branched or crosslinked materials, and (iii) the use of monomers incorporating both furan and maleimide end groups (A2B or AB2 systems), which lead to hyperbranched structures. The application of the retro-DA reaction to the ensuing polymers confirmed their thermoreversible character. (c) 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013, 51, 2260-2270
keywords
REVERSIBLE CLICK CHEMISTRY; RENEWABLE RESOURCES; MACROMOLECULAR MATERIALS; VEGETABLE-OILS; PLANT OILS; FURAN; POLYMERS; SERVICE; SCIENCE
subject category
Polymer Science
authors
Vilela, C; Silvestre, AJD; Gandini, A
our authors
Alessandro Gandini
Researcher
Armando Jorge Domingues Silvestre
Full professor
Carla Vilela
Principal Researcheracknowledgements
The authors wish to thank FCT (Fundacao para a Ciencia e Tecnologia) and POPH/FSE for a doctorate grant to Carla Vilela (SFRH/BD/44884/2008) and Associate Laboratory CICECO funding (strategic project Pest-C/CTM/LA0011/2011).