Thermo-physicochemical investigation of molecular interactions in binary combination (dimethyl carbonate plus methyl benzoate)
authors Jyothirmai, G; Nayeem, SM; Khan, I; Anjaneyulu, C
nationality International
journal JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
author keywords Density; Sound speed; Excess parameters; Prigogine-Flory-Patterson theory; Theory of topology; SRK/PR EoS; Activity coefficients; Nonlinear equations
keywords EQUATION-OF-STATE; LIQUID-MIXTURES; THERMODYNAMIC PROPERTIES; PHYSICAL-PROPERTIES; EXCESS PROPERTIES; 308.15 K; TOPOLOGICAL ASPECTS; REFRACTIVE-INDEXES; DIETHYLENE GLYCOL; ETHYL BENZOATE
abstract To probe the nature of interaction and its deeds with temperature in the binary combination (dimethyl carbonate + methyl benzoate), the density (rho)/speed of sound (u) be established for the total mole fraction array at T = (308.15, 313.15 and 318.15) K and at atmospheric pressure. Sign with magnitude of evaluated excess molar volume (V-m(E)) was inspected and comprehensive analysis elucidated not only pervasiveness of strong molecular interactions between molecules but also its transform with temperature. Additional, strong interactions are properly hold up by partial and excess partial molar volume ((V) over bar (m), (V) over bar (E)(m), (V) over bar (E,infinity)(m)). Additionally, relative association (R-A), Lennard-Jones repulsive power (n), excess isentropic compressibility (K-s(E)), partial and their excess partial molar isentropic compressibility ((K) over bar (m), (K) over bar (E)(m)), excess values of isobaric thermal expansion coefficient (alpha(E)(P)), isothermal compressibility (k(T)(E)), intermolecular free length (L-f(E)), acoustic impedance (Z(E)), ultrasonic speed (u(E)) were evaluated and confirmed the deductions of V-m(E). By Redlich-Kister equation, standard deviations are computed through coefficients for excess parameters. At T = 308.15 K, V-m(E) is correlated by theories of Prigogine-Flory-Patterson (PFP)/topology/Soave-Redlich-Kwong (SRK)/Peng-Robinson (PR) cubic equation of states; prophesied first-order derivatives of thermodynamic potentials; using semi-empirical equations, excess chemical potential/activity coefficients/theoretical speeds are estimated and correlated. Further, microscopic molecular properties are assessed at all temperatures by Sehgal's equations on nonlinear relations.
publisher SPRINGER
issn 1388-6150
year published 2018
volume 132
issue 1
beginning page 693
ending page 707
digital object identifier (doi) 10.1007/s10973-017-6926-8
web of science category Thermodynamics; Chemistry, Analytical; Chemistry, Physical
subject category Thermodynamics; Chemistry
unique article identifier WOS:000426795200066
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journal impact factor 2.731
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