Modeling Hydrate Dissociation Curves in the Presence of Hydrate Inhibitors with a Modified CPA EoS

resumo

A modified CPA equation of state has been applied for the description of noninhibited hydrates. In this work, this model is applied to the description of dissociation curves of hydrates inhibited by six thermodynamic inhibitors (methanol, ethanol, MEG, DEG, TEG, and glycerol), while also focusing on promoting a correct simultaneous description of SLE and VLE between the inhibitors and water. The study concern some of the most well-known hydrate formers (methane, ethane, propane, CO2, Xe, and H2S) and mixtures of these gases. The maximum number of binary interaction parameters applied between water and the hydrate inhibitor is two, one for the physical term and one for association. A comparison between this approach and the hydrates model present on Multiflash is reported, revealing that the present approach, while less accurate than Multiflash is still able to correctly describe hydrate inhibition, VLE and LLE, while using a smaller number of parameters.

palavras-chave

EQUATION-OF-STATE; VAPOR-LIQUID-EQUILIBRIUM; MIXTURE CRITICAL LOCUS; AQUEOUS-SOLUTIONS; ETHYLENE-GLYCOL; CARBON-DIOXIDE; PHASE-EQUILIBRIUM; TRIETHYLENE GLYCOL; DIETHYLENE GLYCOL; HYDROGEN-SULFIDE

categoria

Engineering

autores

Palma, AM; Queimada, AJ; Coutinho, JAP

nossos autores

agradecimentos

This work was funded by KBC Advanced Technologies Limited (A Yokogawa Company) under project Extension of the CPA model for Polyfunctional Associating Mixtures. A.M.P. Acknowledges KBC for his post-doctoral grant. This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, FCT ref. UID/CTM/50011/2019, financed by national funds through the FCT/MCTES.

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