resumo
Organic cages have gained increasing attention in recent years as molecular hosts and porous materials. Among these, barrel-shaped cages or molecular nanobarrels are promising systems to encapsulate large hosts as they possess windows of the same size as their internal cavity. However, these systems have received little attention and remain practically unexplored despite their potential. Herein, we report the design and synthesis of a new trigonal prismatic organic nanobarrel with two large triangular windows with a diameter of 12.7 angstrom optimal for the encapsulation of C-60. Remarkably, this organic nanobarrel shows a high affinity for C-60 in solvents in which C-60 is virtually insoluble, providing stable solutions of C-60.
palavras-chave
CAGE COMPOUNDS; CHEMISTRY; FULLERENES; FUNCTIONALIZATION; TRANSFORMATION; SEPARATION; BINDING
categoria
Chemistry
autores
Bera, S; Das, S; Melle-Franco, M; Mateo-Alonso, A
nossos autores
Manuel Melle-Franco
Investigador PrincipalProjectos
Projeto de Investigação Exploratória: Manuel Melle (IF Manuel Melle)
CICECO - Aveiro Institute of Materials (UIDB/50011/2020)
CICECO - Aveiro Institute of Materials (UIDP/50011/2020)
Associated Laboratory CICECO-Aveiro Institute of Materials (LA/P/0006/2020)
agradecimentos
This work was carried out with support from the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country, Diputacion de Guipuzcoa, Gobierno Vasco (PIBA_2022_1_0031 and BERC programme) and Gobierno de Espana (This publication is part of the projects PID2021-124484OB-I00 and CEX2020-001067-M financed by MCIN/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR). Project (PCI2022-132921) funded by the Agencia Estatal de Investigacion through the PCI 2022 and M-ERA.NET 2021 calls. Technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF) is acknowledged. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant Agreement No. 722951). This work was funded by the European Union under the Horizon Europe grant 101046231. Support through the project IF/00894/2015 and within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020, UIDP/50011/2020 & LA/P/0006/2020, financed by national funds through the FCT/MEC (PIDDAC) is gratefully acknowledged.