Decaaquadioxobis[mu(3)-N-(phosphonomethyl)iminodiacetato] dimanganesedivanadium dihydrate
authors Cunha-Silva, L; Shi, FN; Klinowski, J; Trindade, T; Rocha, J; Paz, FAA
nationality International
journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords X-RAY-DIFFRACTION; HYDROTHERMAL SYNTHESIS; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; MAGNETIC-BEHAVIOR; HYBRID FRAMEWORK; N-(PHOSPHONOMETHYL)IMINODIACETATE; COMPLEXES; ACID
abstract The crystal structure of the title compound, [Mn2V2(C5H6NO7P) O-2(2)(H2O)(10)] center dot 2H(2)O, contains a centrosymmetric dimeric [V2O2(pmida)(2)](4-) unit [ where H(4)pmida is N-(phosphonomethyl) iminodiacetic acid] connecting two neighbouring Mn2+ cations through the phosphonate groups. The crystal structure is characterized by the presence of an extensive network of strong and highly directional O-H center dot center dot center dot O hydrogen bonds, involving the water molecules ( coordinated and uncoordinated) and the functional groups of pmida(4-).
publisher BLACKWELL PUBLISHING
issn 1600-5368
year published 2007
volume 63
beginning page M372
ending page M375
digital object identifier (doi) 10.1107/S1600536806054675
web of science category Crystallography
subject category Crystallography
unique article identifier WOS:000245187300048
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