Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride


In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.






Fernandes, JA; Gomes, AC; Figueiredo, S; Gago, S; Ribeiro-Claro, PJA; Goncalves, IS; Paz, FAA

nossos autores


We wish to thank Dr Martyn Pillinger (CICECO, University of Aveiro) and Dr Andre D. Lopes (University of the Algarve) for their collaboration in the preparation of this communication. We are also grateful to Fundacao para a Ciencia e a Tecnologia (FCT, Portugal) for their general financial support, for the post-doctoral research grant SFRH/BPD/63736/2009 (to JAF), SFRH/BPD/25269/2005 (to SG), SFRH/BD/45116/2008 (to SF) and for specific funding toward the purchase of the single-crystal diffractometer. We also wish to thank the Associated Laboratory CICECO for a research grant to AG.

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