|
authors |
Silva, P; Fernandes, JA; Paz, FAA |
|
nationality |
International |
|
journal |
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
|
keywords |
COORDINATION POLYMERS; DICARBOXYLATE LIGANDS; MAGNETIC-PROPERTIES; MALONATE HYDRATE; GADOLINIUM(III); NETWORKS; ACID |
|
abstract |
The asymmetric unit of the title compound, {[Ce(C3H2O4)Cl-(H2O)(3)]center dot 0.5H(2)O}(n), contains a Ce3+ atom coordinated by a chloride anion, three water molecules and a malonate ligand, and one water molecule of crystallization with a factor of occupancy of 50%. The malonate ligand is bonded to three different symmetry-related metal atoms yielding a one-dimensional coordination polymer running parallel to the a axis. A supramolecular network composed of strong and highly directional O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds ensures a close and effective packing of adjacent polymeric chains. |
|
publisher |
INT UNION CRYSTALLOGRAPHY |
|
issn |
2056-9890 |
|
year published |
2010 |
|
volume |
66 |
|
beginning page |
M1514 |
|
ending page |
U355 |
|
digital object identifier (doi) |
10.1107/S1600536810044727 |
|
web of science category |
Crystallography |
|
subject category |
Crystallography |
|
unique article identifier |
WOS:000284831000018
|
