Sofia M. Bruno

• Investigadora no laboratório associado CICECO, desde 2019
• Bolseira de Pós-Doutoramento no laboratório associado CICECO, 2009-2019
• Técnica de análise por difracção de raios-X, Laboratório Central de Análises da Universidade de Aveiro, 2009
• Doutoramento em Química com base curricular, sob orientação da Professora Doutora Isabel Maria de Sousa Gonçalves e co-orientação do Professor Doutor Paulo Jorge de Almeida Ribeiro Claro, subordinado ao tema ”Síntese e estudos estruturais de novos materiais luminescentes”, Universidade de Aveiro, 2009
• Licenciatura em Química, Faculdade de Ciências da Universidade de Lisboa, 2004

• Complexos organometálicos
• Imobilização e impregnação de complexos organometálicos de óxidos e carbonilos
• Catalisadores homogéneos e heterogéneos
• Catálise oxidativa
• Catálise ácida
• Isomerização

• Professora Isabel Gonçalves
• Doutora Anabela Valente
• Doutor Martyn Pillinger
• Doutora Patrícia Neves
• Doutora Ana Gomes
• Doutora Margarida Antunes
• Doutora Tatiana Amarante

• Prof. Isabel Gonçalves
• Prof. Paulo Ribeiro Claro
• Prof. Luís Dias Carlos
• Prof. Carlos Romão (ITQB-UNL)
• Dr Maria Rute Sá Ferreira
• Dr Susana Santos Braga
• Dr Filipe Paz
• Dr Marta Abrantes (IST-UTL)
• Dr Carla Gamelas (ITQB-UNL)

Inês Silva - MSc student in Chemistry

Estudos catalíticos de (pré)catalisadores homo-/heterogéneos em catálise ácida

(pré)Catalisadores heterogéneos

•  “Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids”, Sofia M. Bruno, Ana C. Gomes, Tânia S. M. Oliveira, Margarida M. Antunes, André D. Lopes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Organic & Biomolecular Chemistry, 14 (2016) 3873-3877. DOI
• "Catalytic isomerization of alfa–pinene oxide in the presence of ETS-10 supported ferricinium ions", Sofia M. Bruno, Ana C. Gomes, Ana C. Coelho, Paula Brandão, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 791 (2015) 66-71. DOI 

(pré)Catalisadores homogéneos

• "Efficient isomerization of a-pinene oxide to campholenic aldehyde promoted by a mixed-ring analogue of molybdenocene", Sofia M. Bruno, Anabela A. Valente, Martyn Pillinger, Jeffrey Amelse, Carlos C. Romão, Isabel S. Gonçalves, ACS Sustainable Chem. Eng., 7 (2019) 13639-13645. DOI
• "Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes", Sofia M. Bruno, Isabel S. Gonçalves, Martyn Pillinger, Carlos C. Romão, Anabela A. Valente, Journal of Organometallic Chemistry, 855 (2018) 12-17. DOI
• “Acid-catalysed epoxide ring-opening reactions promoted by organometallic complexes of the type [(η⁵-C₅H₄-R)Mo(CO)₂(η³-C₃H₅)] and [(η⁵-C₅H₅)Mo(CO)₃(CH₂R)]”, Sofia M. Bruno, Ana C. Gomes, Marta Abrantes, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Journal of Organometallic Chemistry, 799-800 (2015) 179-183. DOI
• "Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde", Sofia M. Bruno, Ana C. Gomes, Carla A. Gamelas, Marta Abrantes, Maria Conceição Oliveira, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carlos C. Romão, Iisabel S. Gonçalves, New Journal of Chemistry, 38 (2014) 3172-3180. DOI
• "Isomerization of alfa-pinene oxide in the presence of methyltrioxorhenium(VII)", Sofia M. Bruno, Martyn Pillinger, Fritz E. Kühn, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 35 (2013) 40-44. DOI
• "Isomerization of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes", Sofia M. Bruno, Carla A. Gamelas, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Carlos C. Romão, Isabel S. Gonçalves, Catalysis Communications, 23 (2012) 58-61. DOI

Estudos catalíticos de (pré)catalisadores homo-/heterogéneos na sulfoxidação

•  "Oxidation of sulfides in aqueous media catalyzed by pyrazole-oxidoperoxido-molybdenum(VI) complexes", Sofia M. Bruno, Tatiana R. Amarante, Filipe A. Almeida Paz, Martyn Pillinger, Anabela A.Valente, Isabel S.Gonçalves, Inorg. Chim. Acta, 511 (2020) 119814-119819. DOI

Estudos catalíticos de (pré)catalisadores homo-/heterogéneos na epoxidação de olefinas

(pré)Catalisadores homogéneos

• "High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO₃)_m(2,2'-bipyridine)_n] family", Sofia M. Bruno, Lucie S. Nogueira, Ana C. Gomes, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, New Journal of Chemistry, 42 (2018) 16483-16492. DOI
• “Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex”, Ana C. Gomes, Sofia M. Bruno, Marta Abrantes, Clara I. R. Magalhães, Isabel S. Gonçalves, Anabela A. Valente, Martyn Pillinger, Journal of Organometallic Chemistry, 760 (2014) 205-211. DOI
• "Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst", Salete S. Balula, Sofia M. Bruno, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Duncan J. Macquarrie, James H. Clark, Inorganica Chimica Acta, 387 (2012) 234-239. DOI
• "Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor", Marta Abrantes, Sofia M. Bruno, Cátia Tomé, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 15 (2011) 64-67. DOI
• "Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenum(VI) complexes bearing a bidentate or tetradentate salen-type ligand", Sofia M. Bruno, Salete S. Balula, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carla Sousa, Jacek Klinowski, Cristina Freire, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 270 (2007) 185-194. DOI
• "New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation", Sofia M. Bruno, Cláudia C. L. Pereira, Maria S. Balula, Mariela Nolasco, Anabela A. Valente, Alan Hazell, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 261 (2006) 79-87. DOI
• "Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes", Sofia M. Bruno, Bernardo Monteiro, Maria S. Balula, Filipe M. Pedro, Marta Abrantes, Anabela A. Valente, Martyn Pillinger, Paulo Ribeiro-Claro, Fritz E. Kühn, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 260 (2006) 11-18. DOI

   (pré)Catalisadores heterogenizados em:

        Materiais mesoporosos com estrutura ordenada do tipo MCM-41

• "Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors", Ana C. Gomes, Sofia M. Bruno, Sandra Gago, Rita P. Lopes, David A. Machado, Anna P. Carminatti, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 696 (2011) 3543-3550. DOI
• "Oxidation of ethylbenzene in the presence of an MCM-41-supported or ionic liquid-standing bischlorocopper(II) complex", Sandra Gago, Sofia M. Bruno, Diogo C. Queirós, Anabela A. Valente, Isabel S. Gonçalves Martyn Pillinger, Catalysis Letters, 141 (2011) 1009-1017. DOI
• "Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins", Sofia M. Bruno, José A. Fernandes, Luísa S. Martins, Isabel S. Gonçalves, Martyn Pillinger, Paulo Ribeiro-Claro, João Rocha, Anabela A. Valente, Catalysis Today, 114 (2006) 263-271. DOI

        Organosílica mesoporosa

• “Post-Synthetic Modification of Crystal-Like Periodic Mesoporous Phenylene-Silica with Ferrocenyl Groups”, Ana C. Gomes, Mirtha A. O. Lourenço, Sofia M. Bruno, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 751 (2014) 501-507. DOI
• "Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its application as a catalyst for the oxidation of styrene", Ana C. Gomes, Maria J. Ferreira, Sofia M. Bruno, Nicolas Bion, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, João Rocha, Isabel S. Gonçalves, Dalton Transactions, 42 (2013) 14612-14620. DOI
• "Grafting of molecularly ordered mesoporous phenylene-silica with molybdenum carbonyl complexes: efficient heterogeneous catalysts for the epoxidation of olefins", Ana C. Coelho, Salete S. Balula, Sofia M. Bruno, João C. Alonso, Nicolas Bion, Paula Ferreira, Martyn Pillinger, Anabela A. Valente, João Rocha, Isabel S. Gonçalves, Advanced Synthesis and Catalysis, 352 (2010) 1759-1769. DOI

       Hidróxidos duplos lamelares

• "Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide", Ana C. Gomes, Sofia M. Bruno, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, Journal of Organometallic Chemistry, 744 (2013) 53-59. DOI
• "Intercalation of a molybdenum eta3-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation", Ana C. Gomes, Sofia M. Bruno, Carla A. Gamelas, Anabela A. Valente, Marta Abrantes, Isabel S. Gonçalves, Carlos C. Romão, Martyn Pillinger, Dalton, 42 (2013) 8231-8240. DOI

       Ciclodextrinas

• "Synthesis and characterization of CpMo(CO)3(CH2PhCO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in Olefin Epoxidation Catalysis", Ana C. Gomes, Sofia M. Bruno, Cátia Tomé, Anabela A. Valente, Martyn Pillinger, Marta Abrantes, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 730 (2013) 116-122. DOI

       Redes metalo-orgânicas

• "Photoluminescent Metal-Organic Frameworks: Rapid Preparations, Catalytic Activity and Framework Relationships", Patrícia Silva, Duarte Ananias, Sofia M. Bruno, Anabela A. Valente, Luís Dias Carlos, João Rocha, Filipe A. Almeida Paz, European Journal of Inorganic Chemistry, 2013 (2013) 5576-5591. DOI
• "Thermal transformation of a layered multi-functional network into a metal-organic framework based on a polymeric organic linker", Patrícia Silva, Fabiana Vieira, Ana C. Gomes, Duarte Ananias, José A. Fernandes, Sofia M. Bruno, Rosário Soares, Anabela A. Valente, João Rocha, Filipe A. Almeida Paz, Journal of American Chemical Society, 133 (2011) 15120-15138. DOI

Estudos citotóxicos

• "Structural studies and cytotoxicity of trimethyl(ferrocenylmethyl)ammonium iodide encapsulated in ß-Cyclodextrin", Sofia M. Bruno, José A. Fernandes, Joana Marques, Sara C. Neto, Paulo J. Ribeiro-Claro, Martyn Pillinger, Filipe A. Almeida Paz, Maria Paula M. Marques, Susana S. Braga, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, 32 (2011) 4955-4963. DOI

 Estudos de fotoluminescência

• "Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) β-diketone complex", Sofia M. Bruno, Duarte Ananias, Filipe Almeida A. Paz, Martyn Pillinger, Anabela A. Valente, Luís D. Carlos, Isabel S. Gonçalves, Dalton Trans., 44 (2015) 488-492. DOI
• "Structural and photoluminescence studies of a europium(III) tetrakis(ß-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions", Sofia M. Bruno, Rute A. Sá Ferreira, Filipe A. Almeida Paz, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Inorganic Chemistry, 48 (2009) 4882-4895. DOI
• "MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes", Sofia M. Bruno, Ana C. Coelho, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Anabela A. Valente, Paulo Ribeiro-Claro, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, (2008) 3786-3795. DOI
• "Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu³⁺ ß-diketonate complex", Sofia M. Bruno, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Microporous and Mesoporous Materials, 113 (2008) 453-462. DOI

Polimerização de borohidretos

• "Lanthanide Borohydrido Complexes for MMA Polymerisation: Syndio- versus Iso- Stereocontrol", Denise Barbier-Baudry, Frédéric Bouyer, Ana Sofia Madureira Bruno, Marc Visseaux, Applied Organometallic Chemistry, 20 (2006) 24-31. DOI