Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties

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abstract

A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H(4)bmt)(H(5)bmt)(H2O)(2)]center dot 3H(2)O coordination polymers is presented. The La3+-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu3+- and Tb3+-doped materials are very effective UV-to-visible light converters.

keywords

METAL-ORGANIC FRAMEWORKS; FUNCTIONALITY; LUMINESCENCE; COMPLEXES; DESIGN; TEMPERATURE; SEPARATION; NUMBER; IONS; SIZE

subject category

Chemistry

authors

Vilela, SMF; Firmino, ADG; Mendes, RF; Fernandes, JA; Ananias, D; Valente, AA; Ott, H; Carlos, LD; Rocha, J; Tome, JPC; Paz, FAA

our authors

foto Ana Daniela Gonçalves Firmino

Ana Daniela Gonçalves Firmino

Researcher
foto Anabela Tavares Aguiar Valente

Anabela Tavares Aguiar Valente

Principal Researcher
foto Duarte Ananias

Duarte Ananias

Assistant Researcher
foto Filipe Alexandre Almeida Paz

Filipe Alexandre Almeida Paz

Principal Researcher
foto João Rocha

João Rocha

Full Professor
foto José Alberto Pires Fernandes

José Alberto Pires Fernandes

Post-doc Fellowship
foto Luís Carlos

Luís Carlos

Full professor
foto Ricardo Faria Mendes

Ricardo Faria Mendes

Junior Researcher
foto Sérgio Manuel Felipe Vilela

Sérgio Manuel Felipe Vilela

Post-doc Fellowship

Groups

G1 - Porous Materials and Nanosystems
G2 - Photonic, Electronic and Magnetic Materials
G4 - Renewable Materials and Circular Economy

Projects

Nano-sized Functional Metal-Organic Frameworks Based on Lanthanide Polyphosphonates (PTDC/QUI-QUI/098098/2008)

Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)

acknowledgements

We thank FCT, the European Union, QREN, FEDER, COMPETE and CICECO (PEst-C/CTM/LA0011/2011). We further wish to thank FCT for the R&D project PTDC/QUI-QUI/098098/2008 (FCOMP-01-0124-FEDER-010785), the PhD grants no. SFRH/BD/66371/2009 (to SMFV), SFRH/BD/84495/2012 (to ADGF), SFRH/BD/84231/2012 (to RFM), and the post-doctoral grant SFRH/BPD/63736/2009 (to JAF).

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Publication Details

type
Journal Article
year
2013
journal
CHEMICAL COMMUNICATIONS
volume
49
publisher
ROYAL SOC CHEMISTRY
issn
1359-7345
issue
57
digital object identifier
10.1039/c3cc42632g
web of science article identifier
WOS:000320709000012

Journal Metrics (JCR 2019)

Journal Impact Factor
5.996
Journal Impact Factor (5 yrs)
5.818
category normalized journal percentile
81.073

Citations

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