Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations

abstract

In the cavities of unprecedentedly functionalised, spherical, porous capsules of the type {Pentagon} 12{Linker} 30; [{( Mo) Mo5O21(H2O)(6)}(12){Mo2O4( ligand)}(30)](n-) reactions with the ligands - i.e. at the internal shell surfaces - can be performed, in the present case deliberate aquation/hydration and deprotonation reactions at the linker fragments {(Mo2O4)C2O4H}(+) similar to that reported in the literature for [(NH3)(5)CoC2O4H](2+) in solution.

keywords

SUPRAMOLECULAR ASSEMBLIES; PROTEIN STABILITY; AQUEOUS-SOLUTION; EN-ROUTE; WATER; GUANIDINIUM; HOFMEISTER; CHEMISTRY; CATIONS

subject category

Chemistry

authors

Muller, A; Toma, L; Bogge, H; Henry, M; Haupt, ETK; Mix, A; Sousa, FL

our authors

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