Sustainable synthesis of a catalytic active one-dimensional lanthanide-organic coordination polymer

abstract

Rationalization of the synthetic conditions allowed the predictable fast sustainable preparation of [La-2(H(3)nmp)(2)(H2O)(4)]center dot 4.5H(2)O having a 1D coordination polymer. The material exhibits a remarkable chemical stability, can be converted into other layered compounds, and is an excellent catalyst surpassing other related materials.

keywords

CRYSTAL SIZE; FRAMEWORKS; LINKER; PHOTOLUMINESCENCE; CAPTURE; DESIGN

subject category

Chemistry

authors

Mendes, RF; Silva, P; Antunes, MM; Valente, AA; Paz, FAA

our authors

Other

acknowledgements

Fundacao para a Ciencia e a Tecnologia (FCT, Portugal), the European Union, QREN, FEDER through Programa Operacional Factores de Competitividade (COMPETE), and CICECO-Aveiro Institute of Materials (Ref. FCT UID/CTM/50011/2013), financed by national funds through the FCT/MEC and when applicable co-financed by FEDER under the PT2020 Partnership Agreement.; We wish to thank FCT for funding the R&D FCOMP-01-0124-FEDER-041282 (Ref. FCT EXPL/CTM-NAN/0013/2013), and CICECO for specific funding towards the purchase of the single-crystal diffractometer. FCT is also gratefully acknowledged for the PhD grants No. SFRH/BD/84231/2012 and SFRH/BD/46601/2008 (to RFM and PS, respectively), and the post-doctoral grant No. SFRH/BPD/89068/2012 (to MMA). The authors also gratefully acknowledge the European Synchrotron Radiation Facility (ESRF, Grenoble, France) for approving the experiments CH-3692 (ID31) and CH-4254 (ID22).

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