abstract
A novel 3-D binary copper(I) polymer [Cu(IN)](n) (1, IN = isonicotinate) has been solvothermally synthesized. 1-D [Cu(IN)] chains of 1 are interconnected by weak metallophilic (Cu center dot center dot center dot Cu) interactions to form a 3-D net. The theoretical band structure and photocatalytic and fluorescence properties have also been studied.
keywords
COPPER IODIDE CLUSTERS; THERMOCHROMIC-LUMINESCENCE; COORDINATION POLYMERS; SOLVOTHERMAL SYNTHESIS; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURES; COMPLEXES; NETWORKS; PHOTOLUMINESCENCE; PHOSPHORESCENCE
subject category
Chemistry
authors
Zhou, J; Tan, XF; Hu, FL; Zou, HH; Paz, FAA; Fu, LS; Zhao, RQ
our authors
Filipe Alexandre Almeida Paz
Principal Researcher
Lianshe Fu
Assistant Researcheracknowledgements
This work was supported by the NNSF of china (No. 21163022), the NSF of Chongqing municipality (No. cstc2014jcyjA50002, cstc2015jcyjBX0117), and the Program for Excellent Talents in Chongqing Higher Education Institutions. We wish to thank Fundacao para a Ciencia e a Tecnologia (FCT, Portugal), the European Union, QREN, FEDER through Programa Operacional Factores de Competitividade (COMPETE), and CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT Ref. UID/CTM/50011/2013), financed by the national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement. The authors are also grateful to Chongqing Normal University for financial support (14CSLJ02, 13XLZ07).