CICECO » Evaluation of the solvent structural effect upon the vapor - liquid equilibrium of [C(4)C(1)im][Cl] + alcohols

authors	Chouireb, N; Khan, I; Crespo, EA; Oliveira, MB; Llovell, F; Vega, LF; Tafat-Igoudjilene, O; Kaci, AA; Santos, LMNBF; Carvalho, PJ; Coutinho, JAP
nationality	International
journal	FLUID PHASE EQUILIBRIA
author keywords	Vapor-liquid equilibrium; 1-Butyl-3-methylimidazolium chloride; Alcohols; Isomers; Soft - SAFI'; Activity coefficients; Binary mixtures; Alkyl chain length
keywords	DIRECTIONAL ATTRACTIVE FORCES; TERNARY-SYSTEM ETHANOL; IMIDAZOLIUM IONIC LIQUIDS; SOFT-SAFT EQUATION; 2-DIMENSIONAL CORRELATION; EXTRACTIVE DISTILLATION; SOLUBILITY BEHAVIOR; PHASE BEHAVIOR; BINARY-SYSTEMS; COSMO-RS
abstract	A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1-butyl-3-methylimidazolium chloride, [C(4)C(1)im][CI], and methanol, propan-1-ol, propan-2-ol, butan-1-ol, butan2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan-1-01, was carried out at three different system pressures (0.1, 0.07 and 0.05 MPa). Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols. (C) 2017 Elsevier B.V. All rights reserved.
publisher	ELSEVIER SCIENCE BV
issn	0378-3812
year published	2017
volume	440
beginning page	36
ending page	44
digital object identifier (doi)	10.1016/j.fluid.2017.02.016
web of science category	Thermodynamics; Chemistry, Physical; Engineering, Chemical
subject category	Thermodynamics; Chemistry; Engineering
unique article identifier	WOS:000399518300004