COSMO-based/Aspen Plus process simulation of the aromatic extraction from pyrolysis gasoline using the 1[4empy] [NTf2] + [emim] [DCA]} ionic liquid mixture
authors Larriba, M; de Riva, J; Navarro, P; Moreno, D; Delgado-Mellado, N; Garcia, J; Ferro, VR; Rodriguez, F; Palomar, J
nationality International
journal SEPARATION AND PURIFICATION TECHNOLOGY
author keywords Aromatic-aliphatic separation; Ionic liquids; Aspen Plus; COSMO-RS; Process simulation
keywords LIQUID-LIQUID-EXTRACTION; IONIC LIQUIDS; N-HEPTANE; CONCEPTUAL DESIGN; AQUEOUS-SOLUTIONS; BINARY-MIXTURES; NAPHTHA FEED; SEPARATION; TOLUENE; EQUILIBRIA
abstract The ionic liquids (ILs) have been widely studied as potential replacements of conventional solvents in the extraction of aromatic hydrocarbons from alkanes. However, most of the literature is focused in obtaining liquid liquid equilibria experimental data without studying the complete extraction and IL regeneration process. In this paper, a computer-aided methodology combining COSMO-based molecular simulations and Aspen Plus process simulations has been used to study the extraction process of aromatic hydrocarbons from pyrolysis gasoline employing a binary mixture of 1-ethyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide ([4empy] [NTf2]) and the 1-ethyl-3-methylimidazolium dicyanamide aemim][DCAD ILs as solvent. An extensive comparison (more than 600 points) between experimental data and the predictions obtained by the COSMO-based thermodynamic model of liquid liquid and vapor liquid equilibria and ILs physical properties was made for validation purposes. Process simulations were performed in three system configurations: with one, two, or three flash distillations in the IL recovery section. The potential advantage of using binary IL-IL mixture as extracting solvent was studied in the whole range of composition. The configuration with three flash distillations and the binary IL -IL mixture with a 75% of [4empy] NTf2 were selected as the optimal conditions to increase aromatic recovery and purity, improving the separation performance respect to the neat ILs.
publisher ELSEVIER SCIENCE BV
issn 1383-5866
year published 2018
volume 190
beginning page 211
ending page 227
digital object identifier (doi) 10.1016/j.seppur.2017.08.062
web of science category Engineering, Chemical
subject category Engineering
unique article identifier WOS:000413378100023
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