abstract
Hierarchical BEA zeolite was prepared through desilication or desilication followed by acid treatment. The catalytic performance of BEA zeolite samples was evaluated using Friedel-Crafts acylations with two substrates of different molecular sizes, furan (5.7 angstrom) and benzofuran (6.9 angstrom), in the presence of acetic anhydride as acylating agent. The application of the simplified Langmuir-Hinshelwood kinetic model showed that the size of the substrate leads to different catalytic activities, with improved rate constant and turnover frequency (TOF) solely in the presence of benzofuran for both desilicated and further acid treated samples. The mesopores developed during the zeolite treatments have an important role as transportation channels by reducing diffusion limitations. The application of Quantitative Structure-Property Relationships (QSPR) allowed the finding of the most relevant properties of the zeolite and substrate with impact on the catalytic parameters.
keywords
FINE CHEMICALS SYNTHESIS; SOLID SOLVENTS; ACETYLATION; CATALYSTS; ANISOLE; DESILICATION; PERFORMANCE
subject category
Chemistry
authors
Nunes, N; Carvalho, AP; Elvas-Leitao, R; Martins, F; Fernandes, A; Rocha, J; Martins, A
our authors
João Rocha
Full Professoracknowledgements
This research was funded by Fundacao para a Ciencia e a Tecnologia (FCT) through UIDB/00100/2020, UIDP/00100/2020, and LA/P/0056/2020, and Instituto Politecnico de Lisboa (IPL) through Project IPL/2021/ZeoGemini ISEL.